Synthesis of Rhodium (I) Complexes with Mono and Dithiolato Ligands: Application in Catalytic Hydroformylation of Olefins

Autor: Edgar Vargas Malváez, Georgina Pimentel, Gustavo Trujillo, Erika Martin

Publikováno v: Universidad Nacional Autónoma de México
UNAM
Redalyc-UNAM
Journal of the Mexican Chemical Society (México) Num.1 Vol.51
Universidad Autónoma del Estado de México
UAEMEX
Redalyc-UAEMEX

The thiols,1-phenylethanothiol 1 and 2,4-pentanodithiol 2 were synthesised and used to prepare binuclear rhodium species 3, 4 of the type [Rh2( #956; #8722;L)n(cod)2] (L = 1, n = 2; L = 2, n = 1; cod = 1,5cyclooctadiene). NMR and FAB+ mass spectromet

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https://www.redalyc.org/articulo.oa?id=47551107