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A Facile Synthetic Route to a Family of Mn III Monomers and Their Structural, Magnetic and Spectroscopic Studies

Autor: Eric J. L. McInnes, Euan K. Brechin, Sergio Sanz, Alan G. Ryder, Brian D. Kelly, Leigh F. Jones, Edel Houton, Anne-Laure Barra, David Collison

Publikováno v: European Journal of Inorganic Chemistry. 2016:5123-5131

We report a rapid and facile synthetic route to the synthesis of a family of Mn(III) monomers of general formula [Mn(III)F3(H2O)(L1-6)]·xH2O·yMeOH (where L1 = 2,2'-Bipyridyl, x = 2, y = 0 (1′); L2 = 1,10'-Phenanthroline, x = y = 0 (2′); L3 = 6-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::75bf9b712aa6ae9879d7eab0c21ec79d
https://doi.org/10.1002/ejic.201601124

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Bulking up: Hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligands

Autor: Euan K. Brechin, Leigh F. Jones, Seán T. Meally, Sergio Sanz, Edel Houton

Publikováno v: Houton, E, Meally, S T, Sanz, S, Brechin, E K & Jones, L F 2014, ' Bulking up : Hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligands ', Inorganica Chimica Acta, vol. 421, pp. 416-422 . https://doi.org/10.1016/j.ica.2014.06.021

Despite their inherent steric bulk, a combination of 2-hydroxy-1-naphthaldoxime (L1H2) with polyphenolic carboxylate ligands (1-Naphthoate, 9-Anthracene carboxylate) aid the construction and stabilisation of hexanuclear arrays of Fe(III) ions in the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b059a519ceed6ac0fd03c6591ffd3842
https://doi.org/10.1016/j.ica.2014.06.021

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Solvothermal synthesis of discrete cages and extended networks comprising {cr(iii)3o(o2cr)3(oxime)3}2− (r = h, ch3, c(ch3)3, c14h9) building blocks

Autor: Leigh F. Jones, Priyanka Comar, Mateusz B. Pitak, Stergios Piligkos, Euan K. Brechin, Edel Houton, Alan G. Ryder, Simon J. Coles

Publikováno v: Houton, E, Comar, P, Pitak, M B, Coles, S J, Ryder, A G, Piligkos, S, Brechin, E K & Jones, L F 2016, ' Solvothermal synthesis of discrete cages and extended networks comprising {Cr( iii ) 3 O(O 2 CR) 3 (oxime) 3 } 2− (R = H, CH 3, C(CH 3 ) 3, C 14 H 9 ) building blocks ', RSC Advances, vol. 6, no. 77, pp. 73668-73676 . https://doi.org/10.1039/C6RA14811E
Houton, E, Comar, P, Pitak, M B, Coles, S J, Ryder, A G, Piligkos, S, Brechin, E K & Jones, L F 2016, ' Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III) 3 O(O 2 CR) 3 (oxime) 3 } 2-(R = H, CH 3, C(CH 3 ) 3, C 14 H 9 ) building blocks ', RSC Advances, vol. 6, no. 77, pp. 73668-73676 . https://doi.org/10.1039/c6ra14811e

The synthesis, structural and magnetic characterisation of a family of related Cr(iii) cages are reported. Each member comprises {Cr(iii)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, re

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dceda27d40f79b34d2db4bd009bf4aa1
http://hdl.handle.net/10379/11990

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Accidentally on purpose: construction of a ferromagnetic, oxime-based [MnIII2] dimer

Autor: Stergios Piligkos, Junjie Liu, Leigh F. Jones, Joan Cano, Stephen Hill, Euan K. Brechin, Edel Houton, Ross Inglis, Alessandro Prescimone

Publikováno v: Dalton Transactions. 40:9999

The serendipitous self-assembly of the complex [Mn(III)(2)Zn(II)(2)(Ph-sao)(2)(Ph-saoH)(4)(hmp)(2)] (1),whose magnetic core consists solely of two symmetry equivalent Mn(iii) ions linked by two symmetry equivalent -N-O- moieties, provides a relativel

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a53dd9ad9efad59c4f67c685beab5b9b
https://doi.org/10.1039/c1dt11118c

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