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Publikováno v:
European Journal of Inorganic Chemistry. 2008:4530-4537
This work introduces a bis(cysteine) ligand to build a small peptidic model system of hydrogenase enzymes. Fe(C5H4CO–Cys–OMe)2 (LH2) has been employed as a chelate for an iron–carbonyl complex, which mimics two essential structural properties o