Zobrazeno 1 - 10
of 111
pro vyhledávání: '"Eberhard Gmelin"'
Publikováno v:
Journal of Alloys and Compounds. 372:17-24
Nd1-xSrxCoO3 polycrystals have been prepared in the compositional range 0 0) is observed for x > 0.4. All other compounds show activated behaviour: drho/dT < 0. A higher order transition is observed in the heat conductivity kappa(T) and the thermopow
Publikováno v:
The Journal of Chemical Thermodynamics. 35:1469-1487
Standard values of Gibbs free energy, entropy, and enthalpy of Na 2 Ti 6 O 13 and Na 2 Ti 3 O 7 were determined by evaluating emf-measurements of thermodynamically defined solid state electrochemical cells based on a Na–β″-alumina electrolyte. T
Autor:
Eberhard Gmelin
Publikováno v:
physica status solidi (b). 236:19-22
The heat capacity of AuTe 2 I was measured in the temperature range of 0.7 K < T < 100 K. The resulting low temperature limiting Debye temperature and electronic contribution were determined to be θ 0 = (140 ± 1.5) K and γ = (1.54 ± 0.04) mJ/mol
Low temperature heat capacity and thermodynamic standard values at 298.15 of β-eucryptite (LiAlSiO4)
Autor:
Eberhard Gmelin
Publikováno v:
Thermochimica Acta. 399:241-244
We report measurements of the heat capacity of the one-dimensional ionic conductor β-eucryptite (Li x Al x Si 1−2 x O 4 ) over the temperature range 1.5–320 K. The entropy and enthalpy at 298.15 K were found to be S °(298.15)=(105.34±0.7) J/mo
Autor:
Eberhard Gmelin, W. Schnelle
Publikováno v:
Thermochimica Acta. 391:41-49
The paper reviews measuring and data computation procedures in heat-step calorimetry, for small samples ( T C p of 1% or lower. The basic features of the method are strictly adiabatic condition at the beginning of each heat capacity measuring point,
Publikováno v:
Scandinavian Journal of Metallurgy. 31:34-51
Certain ternary intermetallic compounds formed between rareearth and transition metals are of particular interest, since their high saturation magnetization and strong, uniaxial, magnetocrys-talline anisotropy are of advantage for the practical appli
Publikováno v:
Journal of Alloys and Compounds. 326:317-320
A thin film of Pr 0.5 Sr 0.5 MnO 3 was prepared by laser ablation technique. The film (2500 A) shows a ferromagnetic (FM) ordering at 250 K for 200 G field followed by a second transition into an antiferromagnetic (AF) state around 150 K. By applying
Autor:
Walter Schnelle, Eberhard Gmelin
Publikováno v:
Journal of Physics: Condensed Matter. 13:6087-6094
The heat capacity of three pure (n, p≤2×1016 cm-3) germanium crystals with different isotopic compositions was measured in the temperature range from 2.8 K to 100 K. These samples, one made of enriched 70Ge (95.6%), Ge of natural isotopic composit
Publikováno v:
physica status solidi (b). 225:443-448
The anomalous metal-insulator transition in BaCo 1-x Ni x S 2-y is identified as a triggered phase transition based on strong coupling between a magnetic and a structural order parameter. In particular, we observe a second-order paramagnetic-antiferr
Autor:
G. H. Rao, K. Bärner, I. El-Kassab, L. Haupt, N. Hamad, N. V. Kasper, U. Sondermann, Eberhard Gmelin
Publikováno v:
Journal of Alloys and Compounds. :145-148
We present X-ray diffraction, magnetization, electrical resistivity, and magnetoresistance data for Nd 0.66 (Sr 1-y Li y ) 0.34 MnO 3 ceramics with y = 0, 0.05, 0.1, 0.2 and 0.3 in the temperature range 50 < T < 400 K and in fields up to 0.5 T. We fi