Výsledky vyhledávání - "Eberhard Bothe"

Structural, Spectroscopic, and Proton‐Coupled Electron‐transfer Behavior of Pyrazolyl‐3,5‐bis(benzimidazole)‐Bridged Homo‐ and Heterochiral Ru II Ru II , Os II Os II , and Os II Ru II 2,2′‐Bipyridine Complexes

Autor: Papu Biswas, Ulrich Flörke, Kamalaksha Nag, Eberhard Bothe, Supriya Dutta, Sujoy Baitalik

Publikováno v: European Journal of Inorganic Chemistry. 2010:570-588

The homo- and heterobimetallic complexes [(bpy) 2 M II -(H 2 pzbzim)M' II (bpy) 2 ](CIO 4 ) 3 ·nH 2 O (1, 3, 5) and their corresponding deprotonated complexes [(bpy) 2 M II (pzbzim)M' II -(bpy) 2 ](CIO 4 )·nH 2 O (2, 4, 6) [where M", M' II = Ru (1,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e934aab750f3996fc65f06a25734275f
https://doi.org/10.1002/ejic.200900848

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Polynuclear Complexes Containing the Redox Noninnocent Schiff Base Ligand 2‐[( E )‐2‐Mercaptophenylimino]methyl‐4,6‐di‐ tert ‐butylphenolate(2–)

Autor: Thomas Weyhermüller, Eberhard Bothe, Karl Wieghardt, Stephen Sproules, Nabarun Roy

Publikováno v: European Journal of Inorganic Chemistry. 2009:2655-2663

The N,O,S-donor Schiff base ligand 2-[(E)-(2-mercaptophenylimino)methyl]-4,6-di-tert-butylphenolate(2–) (H2L) was deprotonated with triethylamine (2 equiv.) and treated with equimolar amounts of Cu(OAc)2·H2O, PtCl2, Pd(OAc)2, and CoCl2, respective

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dd51f0ecca171bd50d662c02b5713262
https://doi.org/10.1002/ejic.200900168

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Targeted Oxidase Reactivity with a New Redox-Active Ligand Incorporating N2O2 Donor Atoms. Complexes of Cu(II), Ni(II), Pd(II), Fe(III), and V(V)

Autor: Phalguni Chaudhuri, Thomas Weyhermüller, Eberhard Bothe, Chandan Mukherjee

Publikováno v: Inorganic Chemistry. 47:11620-11632

The coordination chemistry of the tetradentate ligand N,N'-bis(2-hydroxy-3,5-di-tert-butylphenyl)-2,2'-diaminobiphenyl H(4)L has been studied with the copper(II), nickel(II), palladium(II), iron(III), and vanadium(V) ions. The ligand is non-innocent

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ccdfac71c43e1d52e78d9ecc49405d01
https://doi.org/10.1021/ic8011734

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Characterization of Three Members of the Electron-Transfer Series [Fe(pda)2]n(n=2−, 1−, 0) by Spectroscopy and Density Functional Theoretical Calculations [pda=Redox Non-innocent Derivatives ofN,N′-Bis(pentafluorophenyl)-o-phenylenediamide(2−, 1.−, 0)]

Autor: Eberhard Bothe, Karl Wieghardt, Klaus Harms, Thomas Weyhermüller, Jörg Sundermeyer, Marat M. Khusniyarov, Eckhard Bill

Publikováno v: Chemistry - A European Journal. 14:7608-7622

The four-coordinate iron complexes, [Fe(III)(pda(2-))(pda(.-))] (1) and [AsPh(4)](2)[Fe(II)(pda(2-))(2)] (2) were synthesized and fully characterized; pda(2-) is the closed-shell ligand N,N'-bis(pentafluorophenyl)-o-phenylenediamido(2-), and pda(.-)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c841f904f9b2cfb78bdd4926bc149557
https://doi.org/10.1002/chem.200800546

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An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands

Autor: Connie C. Lu, Karl Wieghardt, Eckhard Bill, Eberhard Bothe, Serena DeBeer George, Thomas Weyhermüller

Publikováno v: Angewandte Chemie. 120:6484-6487

An investigation of the electronic interplay between ligand radical(s) and a high-valent metal center in the three-member electron-transfer series shown in the picture reveals that, upon oxidation and removal of both ligand radicals, the chromium cen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3670a501bb632dc352ab91b8b6547cf0
https://doi.org/10.1002/ange.200800669

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Molecular and Electronic Structures of Mononuclear Iron Complexes Using Strongly Electron-Donating Ligands and their Oxidized Forms

Autor: Eberhard Bothe, Julia B. H. Strautmann, Eckhard Bill, Serena Debeer George, Thorsten Glaser, Anja Stammler, Thomas Weyhermüller, Hartmut Bögge

Publikováno v: Inorganic Chemistry. 47:6804-6824

The ligand L (2-) (H 2L = N, N'-dimethyl- N, N'-bis(3,5-di- t-butyl-2-hydroxybenzyl)-1,2-diaminoethane) has been employed for the synthesis of two mononuclear Fe (III) complexes, namely, [LFe(eta (2)-NO 3)] and [LFeCl]. L (2-) is comprised of four st

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f67d50756cc009ad968786333da25184
https://doi.org/10.1021/ic800335t

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Trinuclear Copper Complexes with Triplesalen Ligands: Geometric and Electronic Effects on Ferromagnetic Coupling via the Spin-Polarization Mechanism

Autor: Eckhard Bill, Julia B. H. Strautmann, Anja Stammler, Robert Huenerbein, Stefan Grimme, Erich Krickemeyer, Hartmut Bögge, Maik Heidemeier, Thorsten Glaser, Eberhard Bothe

Publikováno v: Chemistry - A European Journal. 13:9191-9206

A series of trinuclear Cu(II) complexes with the tris(tetradentate) triplesalen ligands H(6)talen, H(6)talen(tBu(2) ), and H(6)talen(NO(2) ), namely [(talen)Cu(II) (3)] (1), [(talen(tBu(2) ))Cu(II) (3)] (2), and [(talen(NO(2) ))Cu(II) (3)] (3), were

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1b3a07e715e81775157cc54cf5ddff6
https://doi.org/10.1002/chem.200700781

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