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pro vyhledávání: '"Earle K. Plyler"'
Autor:
Earle K. Plyler
Publikováno v:
Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry
A precise measurement of the infrared fundamental bands of HBr79 and HBr81 has been made. The two band centers have been found to be 2,558.94 and 2,558.56 cm-1, respectively. Rotational and vibrational constants have been calculated from the observed
Publikováno v:
Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry
Reports discussing bands of common gases that have been tabulated and remeasured wherever necessary from 2 to 16 microns to obtain an accuracy of about 0.03 cm-1 throughout the region and to provide good calibrating points at frequent intervals. Some
Publikováno v:
Journal of research of the National Bureau of Standards. Section A, Physics and chemistry. (2)
The present work deals with the broadening of rotational lines of the carbon monoxide 2–0 band by both argon and hydrogen chloride. A high resolution grating spectrometer with a spectral slit width of 0.07 cm(−1) was used, necessitating only a sm
Publikováno v:
Applied optics. 6(8)
A high resolution Littrow type grating spectrometer designed for four-pass operation in the near ir is described. Using 20-cm gratings, four passed in first and second orders, this instrument achieves a spectral resolution between 0.015 cm(-1) and 0.
Publikováno v:
Journal of Molecular Spectroscopy. 57:138-154
The OH-stretch fundamental of CH 3 OH has been observed with 0.025 cm −1 resolution between 3430 and 3940 cm −1 and the resulting spectrum deconvoluted using the procedure of P. A. Jansson. Approximately 600 lines have been assigned to a total of
Publikováno v:
The Journal of Chemical Physics. 48:4252-4260
The use of low pressures and a high‐resolution spectrometer for the measurement of the absolute line strengths of gases in the near infrared is tested on the first overtone band of carbon monoxide. Measurements are made at pressures from 100 to 500
Publikováno v:
Journal of Molecular Spectroscopy. 32:74-84
Explicit expressions for the matrix elements of the dipole moment have been derived for the 1-0, 2-0, and 3-0 vibration-rotation bands of diatomic molecules. The derivation is based on a cubic dipole moment function and on radial wave functions obtai
Autor:
Earle K. Plyler, W. S. Benedict
Publikováno v:
Canadian Journal of Physics. 35:1235-1241
A summary is given of molecular constants for NH3 and ND3, as derived from high-resolution infrared spectra of a number of fundamental, overtone, and combination bands. Preliminary estimates are given for the equilibrium moments of inertia, the molec
Autor:
Harry C. Allen, Earle K. Plyler
Publikováno v:
The Journal of Chemical Physics. 31:1062-1065
The parallel band of ethane at 2753 cm—1 and the parallel band of ethane‐d6 at 2816 cm—1 have been observed and analyzed. The resultant values of B for C2H6 and C2D6 are 0.6637 cm—1 and 0.4598 cm—1, respectively. From these B values the C
Publikováno v:
Journal of Molecular Spectroscopy. 38:107-117
The line intensities of the five Σ-Σ bands of CO 2 in the 1.43–1.65 μ region have been measured with relatively low sample pressures and high resolution (0.035–0.06 cm −1 ). The data are analyzed to obtain the total band intensities and dipo