Zobrazeno 1 - 10
of 28
pro vyhledávání: '"E.R. Falardeau"'
Publikováno v:
Materials Science and Engineering. 31:161-167
Stage 1–4 compounds of HOPG intercalated with SbF 5 and AsF 5 were carefully prepared and characterized. Optical reflectance was measured from 0.07 to 2.0 eV using in situ techniques; such methods were necessary because surface decomposition always
Publikováno v:
Materials Science and Engineering. 31:261-265
Unusually high room temperature electrical conductivity, higher than that of pure copper, has been observed under certain conditions in graphite intercalated with the strong acid fluorides, antimony pentafluoride and arsenic pentafluoride. Since thes
Publikováno v:
Solid State Communications. 24:377-381
Room temperature measurements of the 0.07–2.0 eV optical reflectance of carefully prepared stage 1–4 AsF5-graphite intercalation compounds have been performed. Stages 1–3 show simple metallic behavior with a well-defined plasma edge. Curve fits
Publikováno v:
Solid State Communications. 24:371-375
We report here studies at room temperature of the electrical conductivity of AsF5-graphite, a lamellar intercalation compound. Compounds with composition C8nAsF5 have been synthesized where n is the stage. Preliminary measurements of basal plane elec
Publikováno v:
Solid State Communications. 27:163-167
NMR and static magnetic susceptibility (χ) measurements on stage 1 AsF5 intercalated graphite (C8AsF5) are presented. The relaxation times, Ti and T2, of the F19 nuclear magnetic resonance were measured over the temperature range 136K – 295K; χ w
Publikováno v:
Solid State Communications. 25:1059-1065
An initial survey of the conduction electron spin resonance is presented for a series of graphite compounds intercalated with acceptor molecules: stages 1–3 AsF 5 , stages 2–5 HNO 3 , and stage 2 Br 2 and ICl. The g-values and lineshapes were stu
Autor:
E.R. Falardeau, Darryl D. DesMarteau
Publikováno v:
Journal of Fluorine Chemistry. 7:409-414
The reaction of potassium pentafluorophenoxide with acid fluorides has been investigated and found to yield pentafluorophenyl esters. The compounds CH 3 C(O)OC 6 F 5 , CF 3 C(O)OC 6 F 5 , CF(O)OC 6 F 5 , CF 3 OOC(O)OC 6 F 5 , and (C 6 F 5 O) 2 CO hav
Publikováno v:
Solid State Communications. 32:631-634
Raman measurements on low stage compounds of graphite intercalated with AsF 5 , HNO 3 and SbCl 5 are reported. The spectrum of the stage 1 C 8 AsF 5 acceptor compound is found to be in sharp contrast with that reported for the donor stage 1 C 8 M ( M
Autor:
Darryl D. DesMarteau, E.R. Falardeau
Publikováno v:
Journal of Fluorine Chemistry. 7:185-195
The reaction of potassium pentafluorophenoxide with phosphorus halides in a variety of oxidation states has been investigated. The new compounds PCl2OC6F5, PF2OC6F5, OPF2OC6F5, PF4OC6F5 and PF3(OC6F5)2 result from the reaction of KOC6F5 with PCl3, PF
Publikováno v:
Materials Science and Engineering. 31:255-259
Recent measurements of room temperature electrical conductivity in AsF5-graphite intercalation compounds have emphasized the need for a re-evaluation of conventional techniques when applied to quasi-two-dimensional materials. We have thoroughly inves