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Autor:
Boris P. Koch, Philippe Schmitt-Kopplin, Matthias Witt, Norbert Hertkorn, E.M. Perdue, Moritz Frommberger
Publikováno v:
Analytical Chemistry. 80:8908-8919
Soils, sediments, freshwaters, and marine waters contain natural organic matter (NOM), an exceedingly complex mixture of organic compounds that collectively exhibit a nearly continuous range of properties (size-reactivity continuum). NOM is composed
Publikováno v:
Journal of Membrane Science, 323 (2). pp. 328-336.
Dissolved organic carbon (DOC) in the oceans is one of the largest dynamic reservoirs of carbon on earth, comparable in size to the atmospheric reservoir of carbon (as CO2) in the atmosphere, or to the amount of carbon in all terrestrial and aquatic
Publikováno v:
Separation and Purification Technology, 56 (3). pp. 383-387.
Dissolved organic carbon (DOC) in the oceans is one of the largest dynamic carbon reservoirs on earth. The composition and fate of this carbon reservoir is of great interest to earth scientists, atmospheric scientists, and biologists who study global
Publikováno v:
Applied Geochemistry. 22:1612-1623
The results of a comprehensive 113Cd NMR study of complexation of Cd2+ by Suwannee River natural organic matter (NOM) are presented and compared with the more familiar behavior of simple systems containing Cd2+ and a single ligand (e.g., ethylenediam
Publikováno v:
Analytical Chemistry. 79:1010-1021
The aromatic region of two-dimensional heteronuclear 1H, 13C NMR spectra of natural organic matter and related materials (e.g., 1H and 13C chemical shifts ranging from approximately 5 to 10 and 80 to 140 ppm, respectively) is highly complex and diffi
Publikováno v:
Analytical Chemistry. 76:6327-6341
The binding of cadmium to Suwannee River natural organic matter (NOM) has been investigated across a broad range of Cd/C ratios (0.00056-0.0056) and pH values (3.5-11) by (113)Cd NMR spectroscopy at two magnetic field strengths (B(0) = 9.4 and 11.7 T
Publikováno v:
Journal of Chromatography A. 807:101-109
Humic substances, extracted as mixtures from soil and surface waters according to their solubility in acids and bases, are relatively high-molecular-mass polyelectrolytes containing aromatic, aliphatic and heterocyclic subunits. The degree of ionizat
Publikováno v:
Water Research. 29:1471-1477
Reverse osmosis (RO) is a rapid, powerful technique for concentrating dissolved organic matter (DOM) in surface and ground waters. The portable RO system used in our research group can process 150–2001 of water per hour with 90% recovery of organic
Autor:
F. Mantoura, J. Ertel, Cindy Lee, G. Peyton, O. Zafirou, E.M. Perdue, Kenneth Mopper, E. Tanoue, P.M. Williams, P. Coble
Publikováno v:
Marine Chemistry. 41:51-60
Key issues to emerge overall from the detailed discussions include, first of all, the uncertainty of the source and nature of the active oxidant, particularly in HTO methods. This major gap in our understanding of the oxidative processes and yields r