Zobrazeno 1 - 10
of 102
pro vyhledávání: '"E.E. Havinga"'
Autor:
Jérôme Cornil, René A. J. Janssen, E.E. Havinga, John A. E. H. van Haare, Joost L. J. van Dongen, Jean-Luc Brédas
Publikováno v:
Chemistry – A European Journal. 4:1509-1522
Can two isolated radical cations (polarons) exist simultaneously on a π-conjugated chain or do they coalesce into a single, doubly charged spinless (bipolaron) deformation? This long-standing question, fundamental to charge transport in conducting p
Autor:
Eric H. J. Hendrickx, Lambertus Groenendaal, E.E. Havinga, M.J. Bruining, E. W. Meijer, Jef A. J. M. Vekemans, Andre Persoons
Publikováno v:
Chemistry of Materials, 10(1), 226-234. American Chemical Society
The Pd-catalyzed cross-coupling reaction involving organostannanes (Stille reaction) is applied to prep. a series of N-t-BOC-protected D-p-A oligopyrroles. After purifn., oligomers with one to four pyrrole units inserted between a 4-nitrophenyl and a
Sergeants-and-soldiers principle in chiral columnar stacks of disc-shaped molecules with C3 symmetry
Publikováno v:
Angewandte Chemie-International Edition, 36(23), 2648-2651. Wiley
Extremely effective cooperative effects operate during the formation of chiral stacks of C3-symmetrical molecules in alkane solvents (a molecule is depicted on the right). The sergeants-and-soldiers principles as well as chiral solvation lead to a pr
Publikováno v:
Angewandte Chemie. 108:696-699
Autor:
J.A.J.M. Vekemans, L. Groenendaal, J. L. J. van Dongen, H. W. I. Peerlings, E.E. Havinga, E. W. Meijer
Publikováno v:
Macromolecules, 28(1), 116-123. American Chemical Society
The Ullmann coupling reaction has been used to polymerize N-t-BOC-2,5-dibromopyrrole into well-defined oligo(pyrrole-2,5-diyl)s. After optimization of the reaction conditions, i.e. using 1 wt equiv of Cu-bronze in DMF at 100 "C for 1 h, oligomers up
Autor:
Rjm Roeland Nolte, Thierry Verbiest, Aj Schouten, Ew Bert Meijer, E.E. Havinga, Ap Persoons, Mn Marcel Teerenstra, Martti Kauranen
Publikováno v:
Scopus-Elsevier
Advanced Materials, 7(7), 641-644. Wiley-VCH Verlag
Advanced materials, 7(7), 641-644. WILEY-V C H VERLAG GMBH
Advanced Materials, 7(7), 641-644. Wiley-VCH Verlag
Advanced materials, 7(7), 641-644. WILEY-V C H VERLAG GMBH
Communication: The influence of chirality on the nonlinear optical properties of poly(isocyanide)s is examined. It is found that the chiral and nonlinear properties can occur on different levels of the molecular structure and can therefore be separat
Publikováno v:
Molecular Crystals and Liquid Crystals, 256, 439-448. Taylor and Francis Ltd.
The synthesis and (chir)optical properties of a highly regioregular optically active 3-substituted polythiophene are reported. Using the McCullough method a regioselectivity of more than 98% is found for the head-to-tail coupling in 3-[2-((S)-2-methy
Autor:
E.E. Havinga, E. W. Meijer
Publikováno v:
Synthetic Metals, 57(1), 4010-4017. Elsevier
We have demonstrated that second harmonic generation (SHG) can be obtained from centrosymmetric crystals of a racemic mixture of chiral molecules. Circular polarization of the fundamental wave is a prerequisite to obtain selectivity in the interactio
Publikováno v:
Angewandte Chemie. 109:2763-2765
Publikováno v:
Angewandte Chemie-International Edition, 35(6), 638-640. Wiley
In two consecutive one-electron oxidations, oligopyrroles substituted with phenyl capping groups (PhPynPh, n = 2–4) can be oxidized reversibly to give stable cation radicals and dications. Spectroelectrochemical studies give direct evidence that di