Zobrazeno 1 - 10
of 158
pro vyhledávání: '"E.C Reynhardt"'
Autor:
L. Latanowicz, E.C. Reynhardt
Publikováno v:
Chemical Physics Letters. 433:444-449
In a recent experimental study of proton transfer in benzoic acid, employing field cycling NMR relaxometry (Chem. Phys. Lett. 402 (2005) 519 ), the authors came to the conclusion that the transition between the quantum and classical regimes is smooth
Publikováno v:
Journal of Molecular Structure: THEOCHEM. 710:111-117
This paper deals with spin-lattice relaxation due to classical jumps and incoherent tunnelling of protons and deuterons in hydrogen bonds in solids. An analysis of experimental spin-lattice relaxation data for carboxylic acids suggests that tunnellin
Autor:
E.C. Reynhardt
Publikováno v:
Concepts in Magnetic Resonance Part A. :20-35
Spin-lattice relaxation mechanisms of nuclear spins in solids in the presence of low concentrations of paramagnetic centers are discussed. Apart from the electron spin-lattice relaxation mechanism, three-spin processes involving two electron spins an
Autor:
E.C. Reynhardt
Publikováno v:
Concepts in Magnetic Resonance Part A. :36-43
Dynamic nuclear polarization of nuclear spins via the solid-state and thermal mixing effects is discussed. Continuous-wave S- and X-band microwave radiation have been employed to measure 13C signal enhancements and polarization times for 13C nuclei i
Publikováno v:
Solid State Nuclear Magnetic Resonance. 20:1-22
13C spin-lattice relaxation times in the laboratory frame, ranging from 1.4 to 36 h, have been measured on a suite of five natural type Ia and Ib diamonds at 4.7 T and 300 K. Each of the diamonds contains two types of fixed paramagnetic centers with
Autor:
E.C. Reynhardt, L. Latanowicz
Publikováno v:
Chemical Physics Letters. 341:561-567
Spin-lattice relaxation theories for classical and tunneling motions of protons in hydrogen bonds are discussed. It is shown that only one of these theories explains the experimentally determined frequency dependence of proton spin-lattice relaxation
Autor:
E.C. Reynhardt, Cornelis J. Terblanche
Publikováno v:
Chemical Physics Letters. 322:273-279
Electron spin–lattice relaxation (SLR) times of P1 and P2 centers have been measured at 300 K at X-band and W-band for one synthetic (type-Ib) and three natural (type-Ia) diamonds using electron paramagnetic resonance spectroscopy. Bi-exponential S
Publikováno v:
Chemical Physics Letters. 310:97-102
13 C spin–lattice relaxation times in the laboratory frame have been measured at 295 K in a field of 4.7 T for two natural type-IIb diamonds using nuclear magnetic resonance spectroscopy (NMR). 13 C spin–lattice relaxation is mainly due to mobile
Publikováno v:
The Journal of Chemical Physics. 109:8471-8477
Spin-lattice relaxation times of P1 centers in a suite of two natural type Ib, two synthetic type Ib, and one natural type Ia diamonds were measured at 9.6 GHz as a function of temperature in the range 300 K>T>4.2 K. An analysis of the results reveal
Publikováno v:
Molecular Physics. 93:323-328