Zobrazeno 1 - 10
of 80
pro vyhledávání: '"E. V. Bryukhova"'
Autor:
G. K. Semin, E. V. Bryukhova
Publikováno v:
Russian Journal of Physical Chemistry A. 84:235-239
The dependence between quadrupole coupling constants and 59Co asymmetry parameters at 77 K was established in the series (π-C5H4X)Co[π-(3)-1,2-B9H8(8-Z)C2HY]. It was shown that a region of the dynamic Opic-Pryce effect can be determined for these c
Publikováno v:
Russian Chemical Bulletin. 56:1986-1990
A coupling equation relating the quadrupole coupling constant (e2 Qq zz ) to the asymmetry parameter (η) of the electric field gradient for a series of cobaltocenium derivatives (59Co NQR) is derived. The estimates of the correlation times of “slo
Publikováno v:
Russian Journal of Physical Chemistry. 81:30-33
The 35Cl NQR frequencies of (Cl3C)3SiCl at 77 K are interrelated with the inverse spin-lattice relaxation times. This interrelation is in the general form described by a hyperbola equation. It is shown that the “crystal effect” can be resolved in
Publikováno v:
Russian Journal of Physical Chemistry. 80:2054-2057
The parameters of the equation relating the quadrupole coupling constant (e 2 Qq zz ) to the asymmetry parameter (η) of 59Co in the series of compounds R1R2R3SnCo(CO)4 and in the series of reference compounds R1R2R3GeCo(CO)4 and [(π-C5H5-n Men)Co(C
Publikováno v:
Russian Chemical Bulletin. 48:906-913
Regularities of transmission of the effect of equatorial and axial substituents were established for a number of chlorine-containing organic compounds of pentatalent phosphorus using35Cl NQR spectra. The field constants of35Cl NQR frequencies of the
Publikováno v:
Russian Journal of Physical Chemistry. 82:499-501
The behavior of 35Cl NQR spectra in Cl5M · OPCl3 complexes is affected by the nature of the metal center and the distortion of its surrounding geometry. In all cases considered, the 35Cl NQR frequencies in the OPCl3 fragment shift toward higher freq
Publikováno v:
Russian Journal of Physical Chemistry A. 89:510-511
The coordination of chlorobenzene to Cr(CO)3 and ClC6H5Cr+ fragments is shown to result in a considerable rise in the NQR frequency of chlorine atoms. The field constant in (chlorobenzene)chromium tricarbonyl was found to grow markedly, relative to p
Publikováno v:
Russian Journal of Physical Chemistry. 80:1352-1354
For the crystallographically Inequivalent positions of the bromine atoms in CBr4, there exists an equation that relates the frequencies v of 79Br NQR to their field constants α = dv/dEz. This equation can be used to determine the strength of the loc
Publikováno v:
Chemical Physics Letters. 272:86-90
The changes in strength of local electric fields at bromine atoms in the BrCH 2 R series of compounds have been determined from a hyperbolic equation of the relationship between the 79 Br NQR frequency and its derivative with respect to electric fiel
Autor:
G. K. Semin, E. V. Bryukhova
Publikováno v:
Russian Chemical Bulletin. 54:1810-1812
The field constant of the NQR frequency of a chlorine atom (35Cl) in a series of arsenic derivatives [R1R2R3AsCl]+M− was estimated from correlations. The field frequency is ∼41.5±3.5 Hz cm kV−1, which is nearly twice as much as that in analogo