Zobrazeno 1 - 10
of 37
pro vyhledávání: '"E. P. Lur'e"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2614-2617
Perfluoropropylene and 2-H-perfluoropropylene alkylate the fluoro derivatives of ethyllene in the presence of SbCl5 to give the polyfluoro and polyfluorochloro derivatives of 2-pentene.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:129-134
1. Perfluoromethacrylic acid derivatives (methyl ester and dimethylamide) easily add carboxylic acids at the C=C bond to give comparatively stableα-hydro-β-acyloxypentafluoroisobutyric acid derivatives. These adducts when heated are cleaved to the
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:106-114
1. Hexafluorobutadiene and sulfur trioxide do not form the Diels-Alder adducts. The primary reaction product is 4-(trifluorovinyl)-3,3,4-trifluoro-1-oxa-2-thiacyclobutane 2,2-dioxide (a 3-sultone). 2. When stored or heated the β-sultone undergoes re
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:992-995
Perfluoro-(2-isobutenyl-1,1,4,4-tetramethyl-1,3-butadiene) yields 1,4 addition products both in nucleophilic addition and in radical chlorination.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:2323-2326
1. A new, convenient method has been developed for the epoxidation of terminal and internal perfluoroolefins by alkali and alkaline-earth hypohalites in alkaline solution in the presence of aprotic solvents. 2. In the presence of nucleophilic and ele
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:853-860
1. Perfluoromethaerylic acid derivatives when reacted with trialkyl phosphites give stable adducts that contain a pentacoordinated phosphorus atom, and specifically are substitutedα-fluorovinyltrialkoxy-fluorophosphoranes. 2. The phosphoranes obtain
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:437-442
1. Interaction of m- and p-fluorophenylmagnesium bromide with perfluoroisobutylene or with methyl perfluoromethacrylate gives the corresponding arylperfluoroisobutylenes and methylα-trifluoromethyl-β-fluoro-β-arylacrylates. 2. Examination of the19
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2410-2415
Autor:
E. P. Lur'e, L. S. Zakharov, L. L. Morozov, M. I. Kabachnik, E. I. Goryunov, V. A. Svoren, T. M. Shcherbina
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1843-1847
1. The formation of α-polyfluoroalkylbenzyl ethers during the catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols is due to alkylation of these alcohols by α-polyfluoroalkylbenzyl dichlorophosphates formed as intermediates in the course
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:206-209
Carboxylic and thiol acids add to perfluoroisobutylene when catalyzed by tertiary amines to give stable adducts.