Zobrazeno 1 - 10
of 14
pro vyhledávání: '"E. N. Shaposhnikova"'
Autor:
E. N. Shaposhnikova, Nadezhda T. Berberova, D.B. Shpakovsky, E. V. Grigor\\'ev, Elena R. Milaeva, Mikhail P. Egorov
Publikováno v:
Russian Chemical Bulletin. 50:716-719
σ-Aryl trans-bistriphenylphosphine complexes based on 2,6-di-tert-butylphenol containing Pt—SnCl3, Pt—GeCl3 groups were synthesized. Oxidation of these compounds gives the corresponding phenoxyl radicals, which were studied by ESR spectroscopy.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ccbc1e32acf23f4424de27e523aa5c48
https://doi.org/10.1023/a:1011333516900
https://doi.org/10.1023/a:1011333516900
Autor:
Boris Tumanskii, Vasily V. Bashilov, S. P. Solodovnikov, V. I. Sokolov, M. N. Nefedova, N. N. Bubnov, O. G. Kalina, E. N. Shaposhnikova
Publikováno v:
Russian Chemical Bulletin. 49:843-846
The influence of structurally different methanofragments attached to [60]fullerene on the spectral parameters of the spin-adducts of phosphoryl radicals with these compounds was studied by ESR spectroscopy. The main direction of attack of phosphoryl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8a96ab65640d5d44e91e542956b96e86
https://doi.org/10.1007/bf02494706
https://doi.org/10.1007/bf02494706
Publikováno v:
Journal of Fluorine Chemistry. 96:47-50
Fluoroaliphatic hydroxyketoradicals prepared by photochemical reduction of the corresponding α-diketones and (i-C3F7)2C⋅C(O)CF3 react with hydrogen abstraction (according to ESR data). The hydroxyketoradicals are shown to dimerize reversibly, and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a378dae4c8df5f03b25b2220079b9d55
https://doi.org/10.1016/s0022-1139(98)00319-4
https://doi.org/10.1016/s0022-1139(98)00319-4
Publikováno v:
Russian Chemical Bulletin. 48:470-473
The addition of element-centered radicals to perfluorinated α-triketones (CF3)2CFCOCOCOC2F5 (1) and (CF3)2CFCOCOCO(CF3)2 (2) was studied by the ESR method. In the case of Si-centered radicals, α-siloxydiketomethyl radicals are formed, which are cha
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9b570c08887282779c62d6a24d7ac9f9
https://doi.org/10.1007/bf02496163
https://doi.org/10.1007/bf02496163
Autor:
Ivan V. Stankevich, N. N. Bubnov, S. R. Sterlin, S. P. Solodovnikov, Anatolii L. Chistyakov, E. N. Shaposhnikova, Boris Tumanskii
Publikováno v:
Russian Chemical Bulletin. 47:2160-2163
The ESR spectra of radical anions formed by reduction of α-diketones RC(O)C(O)CF3 (R=(CF3)2CF, C6F5, (CF3)3C) with metals (Li, Na, K, Mg, Cd, Zn, Hg, In, and TI) in THF were studied. For R=(CF3)2CF and C6F5, the radical anions are formed ascis-isome
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::228a8aa69911e5ce88151aa7ee28e022
https://doi.org/10.1007/bf02494272
https://doi.org/10.1007/bf02494272
Autor:
S. R. Sterlin, N. N. Bubnov, E. N. Shaposhnikova, Boris Tumanskii, A. I. Chernyavskii, S. P. Solodovnikov, Ivan V. Stankevich, Anatolii L. Chistyakov
Publikováno v:
Russian Chemical Bulletin. 47:60-65
The structure and reactivity of α-ketoradicals, derivatives of (CF3)3CC(O)C(O)CF3 (1), were studied by ESR spectroscopy. The photoreduction of α-diketone1 in a solution of cyclohexane in perfluorodipentyl ether results in the formation of radicals
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::41d66551fe053105421d9a104bbe9e84
https://doi.org/10.1007/bf02495510
https://doi.org/10.1007/bf02495510
Autor:
Ivan V. Stankevich, E. N. Shaposhnikova, Anatolii L. Chistyakov, E. A. Avetisyan, C. P. Solodovnikov, N. N. Bubnov, Boris Tumanskii, S. R. Sterlin
Publikováno v:
Russian Chemical Bulletin. 46:1851-1854
The kinetics of hydrogen abstraction from hydrocarbons by the air-stable perfluoroacetyldiisopropylmethyl radical was studied by ESR, and a reaction mechanism was proposed. The degree of delocalization of the unpaired electron in the model C(5)F3−C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::34a56e23c157f99be75163d90c595e4f
https://doi.org/10.1007/bf02503771
https://doi.org/10.1007/bf02503771
Autor:
Vasily V. Bashilov, Boris Tumanskii, E. N. Shaposhnikova, N. N. Bubnov, V. I. Sokolov, S. P. Solodovnikov
Publikováno v:
Russian Chemical Bulletin. 45:2538-2541
The ESR spectra of the radicals resulting from the multiple addition of diisopropoxyphosphoryl radicals to C60 have been studied. The formation of six different types of radical adducts was detected. A structure for the stable product, characterized
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8a97a08cf34d908bc47b40b44747a9dd
https://doi.org/10.1007/bf01431111
https://doi.org/10.1007/bf01431111
Autor:
V. I. Sokolov, V. V. Bashilov, E. N. Shaposhnikova, Boris Tumanskii, N. N. Bubnov, S. P. Solodovnikov
Publikováno v:
ChemInform. 28
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f89c0b85edbbe524ad468c196a74bbb5
https://doi.org/10.1002/chin.199716031
https://doi.org/10.1002/chin.199716031
Publikováno v:
ChemInform. 29
Fluoro- or chlorobenzenes undergo the Friedel-Crafts acylation with perfluoroacyl chlorides ( I ) without complications to give p -halophenylketones ( II ); however, the reaction of I with bromobenzene gives phenylketones ( IV ) and dibromobenzene in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4c1abd11f925bfacb24d3be04da0bcfa
https://doi.org/10.1002/chin.199835088
https://doi.org/10.1002/chin.199835088