Zobrazeno 1 - 10
of 20
pro vyhledávání: '"E. M. Philbin"'
Publikováno v:
J. Chem. Soc. C. :2848-2855
2-(α-Hydroxybenzyl)-2-methoxycoumaran-3-ones are major products in the alkaline hydrogen peroxide oxidation (AFO reaction) of 2′-hydroxy-α-methoxychalcones containing a phloroglucinol type A-ring, while flavonols predominate in the oxidation prod
Autor:
J. E. Gowan, E. M. Gallagher, M. L. Doporto, A. C. Hughes, T. Swain, T. S. Wheeler, E. M. Philbin
Publikováno v:
J. Chem. Soc.. :4249-4256
Both 5 : 8 : 2' trimethoxyflavone (I ; R = Me) and the 2' : 3' : 6'- isomer(II; R = Me) yield 5 : 6 : 2' - trihydroflavone (IV : R = H) on demethylaction by hydridic acid. This result confirms previous views (see Gallagher et., al., J., 1953, 3770) t
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :2630-2634
Configurations have been assigned to the title compounds from their n.m.r. spectra. Cyclisation of cis- and trans-β-(benzylthio)cinnamic acids gave the corresponding 3-benzylthioinden-1-ones; Dieckmann reactions with ethyl β-(benzylsulphonyl)cinnam
Publikováno v:
J. Chem. Soc.. :3770-3777
Publikováno v:
J. Chem. Soc.. :4455-4458
Publikováno v:
J. Chem. Soc.. :860-862
The action of ethanolic potassium cyanide on certain 2- benzylidene- coumaran - 3-ones gives the corresponding flovones
Publikováno v:
J. Chem. Soc.. :510-512
Publikováno v:
J. Chem. Soc. C. :3168-3170
The formation of 3-phenylthioinden-1-ones by cyclisation of α-substituted β-phenylthio-cis-cinnamic acids with phosphorus pentoxide is described; results obtained using other cyclising reagents are also reported.
Publikováno v:
J. Chem. Soc.. :4174-4176
The Auwers synthesis of 2-acylcoumaran-3-ones (III) freom the corresponding o-acyloxy-ω-chloroacetophenones (I; X = CI) is shown almost certainly to involve an internal Claisen condensation of the Baker-Venkataraman type. This result confirms an ear
Publikováno v:
Chemistryindustry. 30