Zobrazeno 1 - 10
of 18
pro vyhledávání: '"E. I. Smyslova"'
Publikováno v:
Russian Chemical Bulletin. 45:1194-1199
19F NMR spectroscopy was used to study the exchange reactions involving 4-fluorothiophenoxides, 4-nitrophenoxides, chlorides, and acetates of arylmercury and triphenylphosphinegold. The analysis of the data on equilibrium constants allows one to obta
Publikováno v:
Russian Chemical Bulletin. 44:1513-1519
It has been shown by the19F NMR method that the relative polarities of nitrogenelement bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and PPh3Au derivatives increase in the order N-H
Publikováno v:
Russian Chemical Bulletin. 43:125-129
The organomercurials RC(HgR')(CN)2 (R = Me, Ph; R1 = Ph, CH2Ph) have been obtained by the action of organomercury hydroxides R'HgOH or acetates R'HgOAc on substituted malonodinitriles RCH(CN)2- (Ph3PAu3O+BF4 reacts with the same nitriles to give orga
Autor:
Viktor P Dyadchenko, Georgii A Shafeev, E. I. Smyslova, K. I. Granberg, M. R. Bruk, Valerii S Petrosyan
Publikováno v:
Soviet Journal of Quantum Electronics. 21:987-990
An investigation was made of the kinetics of pyrolytic precipitation of gold from eight different triphenylphosphine complexes. The precipitation was initiated by copper vapor laser radiation at the interface between a solution of an organometallic c
Autor:
I. A. Mamed'yarova, L. G. Kuz'mina, M. N. Nefedova, E. I. Smyslova, K. I. Grandberg, V. I. Sokolov
Publikováno v:
Russian Chemical Bulletin. 43:1275-1277
Ruthenocene, like ferrocene, reacts with (Ph3PAu)3O+BF4− to afford agem-diaurated derivative CpRuC5H4(AuPPh3)2+BF4−, which is converted into CpRuC5H4AuPPh3 when treated with PPh3. X-ray structural analysis revealed substantial Ru-Au interaction i
Autor:
E. I. Smyslova, A. V. Usatov, L. N. Saitkulova, Lina M. Epstein, Elena S. Shubina, V. A. Nikanorov
Publikováno v:
Russian Chemical Bulletin. 42:2028-2030
The visualization of solid-state reactions of bis-O-metallated phenolphthaleins and xylenolphthaleins (M=HgC6H4OMe, AuPPh3) with bromides, which has been discovered for the first time, was studied by IR and electronic reflectance spectroscopy. The ap
Publikováno v:
Russian Chemical Bulletin. 44:386-387
Autor:
V. P. Dyadchenko, E. I. Smyslova, Yu. T. Struchkov, É. G. Perevalova, Yu.L. Slovokhotov, K. I. Grandberg
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:2529-2536
1. Triphenylphosphine complexes of cyanomethylgold and dichlorocyanomethylgold have been synthesized. 2. The chemical properties of aurated acetonitrile were typical for σ organogold compounds but aurated dichloroacetonitrile recalled the chemical b
Autor:
Yu.L. Slovokhotov, É. G. Perevalova, K. I. Grandberg, V. P. Dyadchenko, Yu. T. Struchkov, E. I. Smyslova
Publikováno v:
Journal of Organometallic Chemistry. 215:269-279
Organogold(1+) compounds have been synthesized by direct auration of cyclopentadiene, cyanoacetic ester and malonitrile with (Ph3PAu)3O+BF4−. An X-ray structural study (λ Mo, 5062 reflections, R = 0.039) of bis(triphenylphosphinegold)malonitrile h
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2417-2419
1. We discovered the reaction of inserting the methylene group at the gold-chlorine bond to give chloromethyl (triphenylphosphine) gold. 2. The triphenylphosphine complexes of acetylacetonate-ferrocenyl-, and acetonylgold react with diazomethane to g