Zobrazeno 1 - 10
of 162
pro vyhledávání: '"E. I. Mysov"'
Publikováno v:
Russian Chemical Bulletin. 53:2774-2781
The reaction of 1-hydrohexafluoroisobutenyloxytrimethylsilane (2a) with cesium fluoride in diglyme leads to elimination of trimethylfluorosilane to form the 1-hydrohexafluoroisobutenolate anion (3), which is silylated with trialkylchlorosilanes at th
Publikováno v:
Russian Chemical Bulletin. 53:1693-1699
During vacuum pyrolysis in a quartz or steel tube, 1-hydrohexafluoroisobutenyloxytrimethylsilane (1) eliminates fluorotrimethylsilane to give perfluoromethacrolein, which was detected by NMR. Similar pyrolysis of silane 1 over KF results in E- and Z-
Autor:
Yu. N. Belokon, A. B. Terent'ev, N. Yu. Kuznetsov, N. A. Kuz'mina, E. I. Mysov, T. T. Vasil'eva, Nikolay S. Ikonnikov
Publikováno v:
Russian Chemical Bulletin. 48:1121-1127
Reformatsky-type addition of esters of α-halogeno carboxylic acids to aldehydes and ketones in the presence of Fe(CO)5 and an activating agent (CBrCl3 or I2) afforded the corresponding esters of β-hydroxy acids in good yields. Possible reaction mec
Publikováno v:
Russian Chemical Bulletin. 48:294-299
The possibility of anodic generation of a solvated proton on a gas-diffusion electrode in an aprotic medium in the presence of carbon dioxide and 1,3-butadiene has been demonstrated. Formic acid was shown to be the only product of the reaction in the
Autor:
Vladimir B. Shur, E. I. Mysov, M. A. Ilatovskaya, S. Rummel, Vladimir A. Likholobov, H. Langguth, S. M. Yunusov, Manfred Wahren
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 132:277-280
It has been shown that the adducts of active carbons with metallic potassium are able to activate C–H bonds of alkanes, ethene and aromatic hydrocarbons and introduce these compounds into the hydrogen–deuterium exchange reactions at room temperat
Publikováno v:
Journal of Fluorine Chemistry. 88:29-35
The electrocatalytical carboxylations of some perfluoroalkylhalides and α,ω-dihaloperfluoroalkanes on copper and stainless steel electrodes in near-and supercritical CO2-methanol mixtures have been investigated. The main products and intermediates
Publikováno v:
Russian Chemical Bulletin. 46:1560-1564
The possibility of synthesizing dihydromuconic acid by cathodic carboxylation of 1,4-dibromobut-2-ene in the liquid CO2-aprotic solvent system was investigated. The low yield of dihydromuconic acid in this reaction was explained by the competing redu
Autor:
S. R. Sterlin, Cynthia A. Lundgren, V. F. Cherstkov, E. I. Mysov, L. I. Denisovich, A. A. Stepanov, Vitali A. Grinberg, N. I. Delyagina
Publikováno v:
Russian Chemical Bulletin. 46:1441-1444
New approaches to the electrochemical synthesis of aryl perfluoroalkyl ethers based on a) the electrooxidation of perfluorocarboxylic acid on a consumable PbO2 anode and b) the simultaneous anodic oxidation of the “aromatic compound-alkaline perflu
Publikováno v:
Russian Chemical Bulletin. 46:1131-1135
It was shown that the current yield of the products of anodic trifluoromethylation of arenes correlates with the adsorptivity and the rate of electrooxidation of arenes on the surface of a platinum electrode.
Autor:
Helmuth Langguth, Siegbert Rummel, M. A. Ilatovskaya, V. S. Lenenko, Vladimir B. Shur, E. I. Mysov
Publikováno v:
Angewandte Chemie. 108:2678-2681