Zobrazeno 1 - 10
of 120
pro vyhledávání: '"E. G. Bykhovskaya"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2161-2164
1. Perfluoro-2-azapropene when passed through a suspension of alkali-metal fluorides in aprotic polar solvents generates the bis(trifluoromethyl)aza anion. 2. Reactions involving (CF3)3N− are a convenient way of inserting the bis(trifluoromethyl)am
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:2188-2191
1. The easily leaving bis(trifluoromethyl)amino group is eliminated as a stable anion when nucleophilic reagents act on bis(trifluoromethyl)carbamoyl fluoride. 2. The similarity in the reactivity of bis(trifluoromethyl)carbamoyl fluoride and the perf
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:640-643
1. The reaction of perfluoroazomethines with trimethylsilyl azide gives previously unreported, stable perfluoroazidoazomethines (perfluoroimidazides). 2. A new rearrangement is reported, by which perfluoroazidoazomethines are converted in good yields
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:2224-2226
1. A number of alkyl perfluoroazapropenyl ethers was synthesized. It was shown that they are capable of alkylating tertiary amines to give the tetraalkylammonium salts of the mesomeric trifluoromethylfluorocarbonyl azanion. 2. The alkyl perfluoroazap
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:399-401
1. The stable 1,1-bis(trifluoromethyl)hydrazine was synthesized by the thermal decomposition of either tert-butyl bis(trifluoromethyl)carbamate or a solution of bis(trifluoromethyl) carbamic acid azide in the presence of water, and its reaction with
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2212-2214
1. Perfluoro-2-azapropene is more electrophilic than perfluoroisobutylene, which is the most electrophilic of the nonfunctional fluoroolefins. 2. The reaction of perfluoro-2-azapropene with trialkyl phosphites gave trialkoxyperfluoroazapropenylfluoro
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2214-2216
1. The reaction of perfluoro-2-azapropene with carboxylic acids gave the (trifluoromethylamino)difluoromethyl esters of the corresponding acids. The latter are heat unstable and, depending on the acyl radical, decompose either to the starting compoun
Publikováno v:
Chemischer Informationsdienst. 8
1. A number of alkyl perfluoroazapropenyl ethers was synthesized. It was shown that they are capable of alkylating tertiary amines to give the tetraalkylammonium salts of the mesomeric trifluoromethylfluorocarbonyl azanion. 2. The alkyl perfluoroazap
Publikováno v:
Chemischer Informationsdienst. 9
1. The reaction of nucleophilic reagents with perfluorodimethylazapropenylamine leads to its dedimerization. 2. The reaction of perfluoro-2-azapropene with dialkylamines and ammonia respectively gave dialkylperfluoroazapropenylamines and the amide of
Publikováno v:
Chemischer Informationsdienst. 7