Zobrazeno 1 - 10
of 15
pro vyhledávání: '"E. D. Totchasov"'
Publikováno v:
Russian Journal of Physical Chemistry A. 84:950-953
The kinematic viscosity and density of the methanol-n-decane system were measured at various temperatures at low n-decane concentrations (over the miscibility range). The theory of free volume with taking into account molecular association was used t
Publikováno v:
Russian Journal of Physical Chemistry A. 83:45-49
The enthalpies of solution of nonelectrolytes in mixed solvents were calculated using the Associated Solution + Lattice thermodynamic model, whose parameters are equilibrium constants, the enthalpies of formation of associates, and the energy of mutu
Publikováno v:
Journal of Structural Chemistry. 49:1120-1123
Chemical shifts (c.s.) of 1H nuclei in methanol are measured for methanol-benzene and methanol-phenanthrene systems. A method to determine the equilibrium constant of the molecular association reaction by NMR spectroscopy data is proposed for systems
Publikováno v:
Russian Journal of Physical Chemistry. 82:222-227
The kinematic viscosity of n-nonane mixtures with propan-1-ol, butan-1-ol, and pentan-1-ol was measured over the temperature range 293.15–313.15 K. For all systems, negative deviations of viscosity from additive values were obtained; the deviations
Autor:
E. D. Totchasov, G. A. Al’per
Publikováno v:
Russian Journal of Physical Chemistry A. 82:71-74
The Helmholtz energy of dipole-dipole interaction (ΣΔdF) and its long-range (ΔdF°) and short-range (ΔdF*) components were calculated for n-pentane-alkane-1-ol (from methanol to dodecane-1-ol) systems at 298.15 K using the Winkelmann statistical
Publikováno v:
Russian Journal of Physical Chemistry A. 81:1623-1626
A method for calculating the solubility of gases in mixed nonaqueous solvents was suggested. The method was based on the theory of molecular association and the simple lattice model. It allowed the solubility of gases in mixed nonaqueous solvents to
Publikováno v:
Russian Journal of Physical Chemistry A. 81:1088-1091
A method for calculating the limiting activity coefficients of liquid nonelectrolytes in binary solvents based on the associated solution + lattice model is suggested. The method can be used to calculate limiting activity coefficients in mixed solven
Publikováno v:
Journal of Structural Chemistry. 48:474-478
A method for calculating the solubility of solid substances in mixed non aqueous solvents is proposed based on the theory of molecular association and a simple lattice model (ASL = Associated Solution + Lattice). This method provides the calculation
Publikováno v:
Russian Journal of Physical Chemistry. 80:1676-1679
This work presents the results obtained in measurements of the kinematic viscosity and density of the methanol-n-nonane, ethanol-n-nonane, and ethanol-n-decane systems at various temperatures and low n-alkane concentrations (within the concentration
Publikováno v:
Russian Journal of Applied Chemistry. 79:34-37
A method was suggested for calculating the molar heat capacity of n-alkanol-n-alkane solutions with account of the molecular association by the free-volume theory from data on the viscosity of these systems.