Zobrazeno 1 - 10
of 549
pro vyhledávání: '"E E, Nifant'ev"'
Autor:
I. B. Goryunova, E. I. Goryunov, A. S. Parshakov, V. I. Privalov, E. E. Nifant'ev, E. G. Il’in
Publikováno v:
Russian Journal of Coordination Chemistry. 45:667-674
The complex formation of TiF4 with the phosphorylated ketone Ph2P(O)CH(Me)CH2C(O)Et (L), containing an asymmetric carbon atom in the aliphatic hydrocarbon group and representing a racemic mixture of enantiomers, was studied by 19F{1H} and 31P{1H} NMR
Publikováno v:
Russian Journal of Coordination Chemistry. 45:340-346
Some peculiarities of the effect of enantiomers of the monodentate ligand on the stereoisomerism of the mixed octahedral tetrafluoride complexes of d0-transition metals are established by the 19F{1Н} and 31Р{1Н} NMR methods for the complex formati
Publikováno v:
Doklady Physical Chemistry. 482:135-139
Effect of enantiomers of a monodentate ligand on the stereoisomerism of mixed octahedral cis-tetrafluoro complexes of d0 transition metals has been studied by 19F{1H} and 31P{1H} NMR by the example of TiF4 complexation in CH2Cl2 with Ph2P(O)CH2CH(OH)
Publikováno v:
Russian Journal of Coordination Chemistry. 44:619-625
The compositions and structures of the products of the reaction of TaF5 with Ph2P(O)(CH2)2C(O)NМе2 (L) in СН3СN and СН2Сl2 are studied by the 19F and 31Р NMR methods. As the hydrocarbon bridge between the Р=О and С=О donor groups in carb
Autor:
T. S. Kukhareva, S. E. Mosyurov, A. O. Pozdeev, E. E. Nifant'ev, M. P. Koroteev, A. M. Koroteev
Publikováno v:
Doklady Chemistry. 480:107-110
Reactions of catechin and dihydroquercetin flavonoids with amino acids containing primary amino groups have been conducted. Amino acids can be used in both electrophilic substitution (Mannich aminomethylation) and electrophilic substitution (acylatio
Publikováno v:
Doklady Physical Chemistry. 479:52-56
The reaction of TiF4 with PhP(O)[CH2C(O)NMe2]2 in CH2Cl2 has been studied by 19F NMR spectroscopy. It has been found that the major reaction products are chelate tetrafluoro complex (η2-L)TiF4 where the ligand is coordinated to the titanium ion thro
Autor:
E. E. Nifant'ev, A. A. Khodak, G. N. Molchanova, Valery K. Brel, I. Yu. Kudryavtsev, I. B. Goryunova, E. I. Goryunov, Tatyana V. Strelkova, T. V. Baulina
Publikováno v:
Doklady Chemistry. 472:21-24
The reaction of methyl- and phenyldichlorophosphonates with phenols in the presence of anhydrous magnesium chloride (catalyst) or magnesium metal (procatalyst) has been used as a simple, efficient, and industrially feasible method for the synthesis o
Autor:
A. S. Parshakov, V. G. Yarzhemskii, E. E. Nifant'ev, I. B. Goryunova, V. V. Danilov, E. I. Goryunov, E. G. Il’in
Publikováno v:
Doklady Chemistry. 471:314-320
The products resulting from the reaction of TiF4 with Ph2P(O)(CH2)2C(O)Me (L') in CH2Cl2 have been studied by 19F{1H} and 31P{1H} NMR spectroscopy. At a twofold excess of L', solution contains cis-TiF4(L')2 (>90%), trans-TiF4(L')2, and fac-[TiF3L3']+
Autor:
E. G. Il’in, G. V. Bodrin, A. S. Parshakov, G. G. Aleksandrov, V. G. Yarzhemskii, E. I. Goryunov, V. V. Danilov, E. E. Nifant'ev
Publikováno v:
Doklady Chemistry. 470:255-259
The crystal structure of TiF4[(Ph2P(O)CH2CH2C(O)NMe2)] chelate (I) was studied by X-ray crystallography, which revealed four crystallographically independent complex molecules of similar structure (1–4). It was found that the molecules are only sli
Autor:
D. V. Argun, G. Z. Kaziev, M. P. Koroteev, T. S. Kukhareva, E. E. Nifant'ev, A. M. Koroteev, S. E. Mosyurov
Publikováno v:
Doklady Chemistry. 468:148-151
The reactivity of dihydroquercetin and catechol flavonoids in acylation, phosphorylation, and aminomethylation reactions was compared. The structure of natural polyatomic phenols was shown to affect markedly their chemical behavior.