Zobrazeno 1 - 10
of 91
pro vyhledávání: '"E B Evans"'
Autor:
Robert J. Crutchley, Glenn P. A. Yap, K.-S Focsaneanu, Christopher E. B. Evans, Peter John Mosher, Maria C. DeRosa
Publikováno v:
Inorganic Chemistry. 42:4864-4872
This study reports new luminescent oxygen sensors in which the luminophore is covalently bound to the polymer matrix and compares their behavior to related sensors in which the luminophore is dispersed within the matrix. The cyclometalated iridium co
Publikováno v:
Macromolecular Symposia. 196:235-248
New luminescent oxygen sensors have been prepared by covalent attachment of iridium complex luminophores to a silicone polymer. The oxygen sensor properties of these novel materials were compared to related sensors in which the luminophore is dispers
Autor:
Mitchell A. Winnik, Ian Manners, Zhibin Wang, Xin Lu, S. Chung, Andrew R. McWilliams, Christopher E. B. Evans
Publikováno v:
Advanced Functional Materials. 12:415-419
Phosphorescent materials that exhibit efficient quenching by oxygen are of interest for a range of sensing applications, including the visualization of pressure distributions arising from airflow over aircraft. A new, single-component processable sid
Publikováno v:
Macromolecular Chemistry and Physics. 202:1768-1775
Investigations on a series of crosslinked poly(ferrocenylsilane) networks that have been prepared via the ring-opening copolymerization of the silicon-bridged [1]ferrocenophane fcSiMe2 (fc = Fe(η-C5H4)2) with controlled amounts of a spirocyclic [1]f
Publikováno v:
Journal of the American Chemical Society. 123:1396-1402
The cyanamide stretching frequencies of the mixed-valence complexes [{Ru(NH3)5}2(μ-L)]3+, trans,trans-[{Ru(NH3)4(py)}2(μ-L)]3+ (py = pyridine), and mer,mer-[{Ru(NH3)3(bpy)}2(μ-L)]3+ (bpy = 2,2‘-bipyridine), where L is the 1,4-dicyanamidobenzene
Autor:
Xiao-Hua Liu, Mitchell A. Winnik, Zhen Pang, Ian Manners, Peter Park, Ahmad Yekta, Yizeng Ni, Xin Lu, Christopher E. B. Evans, Xijia Gu, Andrew R. McWilliams, Raiph Ruffolo
Publikováno v:
Analytical Chemistry. 72:1894-1904
We examine the use of thionylphosphazene-based block copolymers as matrixes for oxygen sensor applications. Poly(aminothionylphosphazene)-b-poly(tetrahydrofuran) (PATPy-PTHFx) block copolymers were prepared via reaction of ring-opened poly(chlorothio
Publikováno v:
New Journal of Chemistry. 24:447-453
Phosphorus(III)-bridged [1]ferrocenophanes cannot be polymerized via transition-metal catalyzed ring-opening polymerization, presumably due to the phosphorus lone pair ligating the catalyst. We have investigated a potential solution to this problem,
Autor:
Robert J. Crutchley, Veniamin V. Kondratiev, Christopher A. White, Christopher E. B. Evans, Ali Reza Rezvani, Mark L. Naklicki
Publikováno v:
Journal of the American Chemical Society. 120:13096-13103
A quantitative study of hole-transfer superexchange in Class II mixed-valence complexes is presented. The free energy of resonance exchange was calculated from metal−metal coupling elements derived from Hush and CNS models and compared to experimen
Publikováno v:
Inorganic Chemistry. 37:6161-6167
Three dinuclear complexes [{mer-Ru(NH3)3(bpy)}2(μ-L)][ClO4]4, where L = 2,5-dimethyl- (Me2dicyd2-), 2,5-dichloro- (Cl2dicyd2-), and unsubstituted 1,4-dicyanamidobenzene dianion (dicyd2-), have been synthesized and characterized by magnetic resonance
Autor:
Christopher E. B. Evans, Mark L. Naklicki, Lisa L. Plante, Christopher A. White, Robert J. Crutchley
Publikováno v:
Inorganic Chemistry. 37:1880-1885
Antiferromagnetic exchange constants were calculated by using the Mulliken−Hush treatment for metal−ligand coupling elements (J. Photochem. Photobiol. A: Chem. 1994, 82, 47) and the valence bond model of antiferromagnetic exchange (Inorg. Chem. 1