Zobrazeno 1 - 10
of 108
pro vyhledávání: '"E A, Rokhlin"'
Publikováno v:
Journal of Fluorine Chemistry. 65:195-201
Mono-, di- and tri-substituted fluorine-containing α-oxides have been shown to enter into reactions with trialkyl phosphites which proceed through cleavage of the CC and CO bonds in the epoxide ring. The trialkoxyphosphorus ylides II , V , VII
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::80ef64084a969b5e12cffb085db5a639
https://doi.org/10.1016/s0022-1139(00)80854-4
https://doi.org/10.1016/s0022-1139(00)80854-4
Publikováno v:
ChemInform. 25
Mono-, di- and tri-substituted fluorine-containing α-oxides have been shown to enter into reactions with trialkyl phosphites which proceed through cleavage of the CC and CO bonds in the epoxide ring. The trialkoxyphosphorus ylides II , V , VII
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d0954715b067be8ce6a146896d39753a
https://doi.org/10.1002/chin.199414218
https://doi.org/10.1002/chin.199414218
Publikováno v:
ChemInform. 21
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7db298a33c673f3b57d688729dd131c3
https://doi.org/10.1002/chin.199018122
https://doi.org/10.1002/chin.199018122
Publikováno v:
ChemInform. 21
By reacting bis(trifluoromethyl)ketene with ethylene glycol, 1,4-butylene glycol, or hydroquinone the corresponding bis-α-hydrohexafluoroisobutyrates are obtained, which on dehydrofluorination with Et3N·BF3 yield bis-pentafluoromethacrylates.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ebca55c8a0abfb20ab36fcf48c67825d
https://doi.org/10.1002/chin.199007141
https://doi.org/10.1002/chin.199007141
Publikováno v:
Russian Chemical Reviews. 58:1145-1156
The reactions involving reduction of electrophilic double bonds (C=C, C=O, C=N, and N=N) with amines (usually tertiary) that contain hydrogen atoms at the α-position have been classified. The key stage in such reactions is formation of an iminium sa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::deed20dc138c87b3e61311cbddb2d4e3
https://doi.org/10.1070/rc1989v058n12abeh003501
https://doi.org/10.1070/rc1989v058n12abeh003501
Autor:
I. L. Knunyants, Yu. V. Zeifman, U. Utebaev, T.V. Lushnikova, Yo.G. Abduganiev, E. M. Rokhlin
Publikováno v:
Journal of Fluorine Chemistry. 6:227-240
Adduct (C2H5)3N·BF3 has proved to be a suitable dehydrofluorinating reagent for preparing highly reactive fluoroolefines through dehydrofluorination of corresponding monohydro derivatives. Its advantage over other dehydrofluorinating agents are demo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::981746b89a84044ce1df2c39e936d57c
https://doi.org/10.1016/s0022-1139(00)83002-x
https://doi.org/10.1016/s0022-1139(00)83002-x
Autor:
E. M. Rokhlin, A. A. Kadyrov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:2143-2149
1. Esters of pentafluoroisopropenylphosphonic acid were obtained by dehydrofluorination of the corresponding esters ofα-hydrohexafluoroisopropylphosphonic acid or the loss of alkyl fluoride from hexafluoroisopropylidenetrialkoxyphosphoranes by the a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aee17b52a475b6f9b6b7bc2084e07db8
https://doi.org/10.1007/bf01094645
https://doi.org/10.1007/bf01094645
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:129-134
1. Perfluoromethacrylic acid derivatives (methyl ester and dimethylamide) easily add carboxylic acids at the C=C bond to give comparatively stableα-hydro-β-acyloxypentafluoroisobutyric acid derivatives. These adducts when heated are cleaved to the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3652b9a6529058e7098335ff40dbfff5
https://doi.org/10.1007/bf00925634
https://doi.org/10.1007/bf00925634
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:124-128
When heated in the presence of a catalytic amount of BF3 etherate,α-trifluoromethyl-β-diethylamino-β-fluoroacrylic acid N, N-dimethylamide is reversibly isomerized toα-trifluoromethyl-β-dimethylamino-β-fluoroacrylic acid N, N-diethylamide. The
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c31675504902ba4fc80bb34d1d065120
https://doi.org/10.1007/bf00925633
https://doi.org/10.1007/bf00925633
Autor:
A A Kadyrov, E M Rokhlin
Publikováno v:
Russian Chemical Reviews. 57:852-863
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aeb7211362666d4d179f97256e23e5ad
https://doi.org/10.1070/rc1988v057n09abeh003395
https://doi.org/10.1070/rc1988v057n09abeh003395