Inversion of Configuration at the Phosphorus Nucleophile in the Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides.

Autor: Muldoon JA; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Varga BR; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Deegan MM; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Chapp TW; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Eördögh ÁM; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Hughes RP; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Glueck DS; Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH, 03755, USA., Moore CE; Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA, 92093, USA., Rheingold AL; Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA, 92093, USA.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2018 Apr 23; Vol. 57 (18), pp. 5047-5051. Date of Electronic Publication: 2018 Mar 23.