Zobrazeno 1 - 10
of 53
pro vyhledávání: '"E, Pivonka"'
Autor:
Rachel A. Carr, Trichina Tucker, Precious M. Newman, Lama Jadalla, Kamayel Jaludi, Briana E. Reid, Damian N. Alpheaus, Anish Korrapati, April E. Pivonka, Valerie J. Carabetta
Publikováno v:
Frontiers in Microbiology, Vol 15 (2024)
Nε-lysine acetylation is recognized as a prevalent post-translational modification (PTM) that regulates proteins across all three domains of life. In Bacillus subtilis, the histone-like protein HBsu is acetylated at seven sites, which regulates DNA
Externí odkaz:
https://doaj.org/article/7b0d04d310f6486d8fcbb728313556d2
Autor:
Mark A. Forman, Caitlin A. Moran, James E. Hall, Don E. Pivonka, Joseph P. Herres, John P. McCauley, Steven Wesolowski
Publikováno v:
The Journal of Organic Chemistry. 81:6862-6866
The diiodobinorsnoutane, bi(5-iodopentacyclo[4.3.0.0(2,4).0(3,8).0(5,7)]non-4-yl) (5), exists in a sterically hindered gauche conformation rather than an anti or an averaged (freely rotating) C2v structure. Density functional theory (DFT) predictions
Publikováno v:
Chemistry - A European Journal. 17:9193-9199
Infrared spectra recorded for 1,5-dimethyl-2,8:4,6-semibullvalenetetracarboxylic acid dianhydride (12) in the condensed and vapor phase clearly prove that in the vapor phase the dianhydride 12 is a homoaromatic ground state semibullvalene.
Autor:
Don E. Pivonka, James Empfield
Publikováno v:
Applied Spectroscopy. 58:41-46
Integration of a Raman probe into a commercially available microwave synthesizer has demonstrated unprecedented utility in understanding chemical processes within the rapidly emerging field of microwave-assisted organic synthesis. The real-time spect
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 47:983-995
The utility of Raman spectroscopy for noninvasive, real-time monitoring of a range of tritium gas labeling reactions has been investigated, using deuterium gas as a model in most cases. Reaction types include organoiridium-catalyzed heteroatom-direct
Autor:
Sparks Richard Bruce, Don E. Pivonka
Publikováno v:
Applied Spectroscopy. 54:1584-1590
Raman spectroscopy has been implemented as an extremely powerful tool for the vibrational analysis of solid-phase synthesis. In this report, the application of both on-line and batch-mode Raman analysis is presented for the comprehensive characteriza
Autor:
Don E. Pivonka
Publikováno v:
Journal of Combinatorial Chemistry. 2:33-38
This report introduces two novel methodologies for the on-bead, functional group quantitation of solid phase synthesis using vibrational spectroscopy. "Analogue bleed" quantitation is an infrared spectroscopic technique in which combinatorial library
Publikováno v:
Applied Spectroscopy. 53:1027-1032
The infrared technology presented in this paper provides a mechanism for the detailed study of PyBOP [(1H-benzotriazole-1-yloxy)tripyrrolidinophosphonium hexafluorophosphate] ester activation in a solid-phase supported chemical system. Prior to this
Autor:
K. M. Kirkland, Don E. Pivonka
Publikováno v:
Applied Spectroscopy. 51:866-873
A strategy for the infrared spectroscopic analysis of drug metabolites in high-pressure liquid chromatography (HPLC) effluent is presented with a primary focus on delivery of metabolite structure as opposed to development of dedicated or automated in
Autor:
Don E. Pivonka, Steven Wesolowski
Publikováno v:
ChemInform. 44
The absolute stereochemistry of chiral drugs is usually established via X-ray crystallography. However, vibrational circular dichroism (VCD) spectroscopy coupled with quantum mechanics simulations offers a rapid alternative to crystallography and is