Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasma

Autor: Xu, Shaojun, Han, Xue, Ma, Yujie, Duong, Thien D., Lin, Longfei, Gibson, Emma K., Sheveleva, Alena, Chansai, Sarayute, Walton, Alex, Ngo, Duc-The, Frogley, Mark D., Tang, Chiu C., Tuna, Floriana, McInnes, Eric J.L., Catlow, C. Richard A., Hardacre, Christopher, Yang, Sihai, Schröder, Martin

Publikováno v: In Cell Reports Physical Science 24 February 2021 2(2)

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Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

Autor: Duong, Thien D., Sapchenko, Sergey A., Da Silva, Ivan, Godfrey, Harry G.W., Cheng, Yongqiang, Daemen, Luke L., Manuel, Pascal, Ramirez-Cuesta, Anibal J., Yang, Sihai, Schröder, Martin

Publikováno v: Duong, T D, Sapchenko, S A, Da Silva, I, Godfrey, H G W, Cheng, Y, Daemen, L L, Manuel, P, Ramirez-Cuesta, A J, Yang, S & Schröder, M 2018, ' Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework ', Journal of the American Chemical Society, vol. 140, no. 47, pp. 16006-16009 . https://doi.org/10.1021/jacs.8b08504

We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102

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https://www.research.manchester.ac.uk/portal/en/publications/optimal-binding-of-acetylene-to-a-nitrodecorated-metalorganic-framework(2e558b0a-311b-4482-bafc-15cc2f2ba190).html