Zobrazeno 1 - 10
of 114
pro vyhledávání: '"Duncan F. Wass"'
Publikováno v:
Organometallics
King, A M, Wingad, R L, Pridmore, N E, Pringle, P G & Wass, D F 2021, ' Rhenium Complexes Bearing Tridentate and Bidentate Phosphinoamine Ligands in the Production of Biofuel Alcohols via the Guerbet Reaction ', Organometallics, vol. 40, no. 16, pp. 2844-2851 . https://doi.org/10.1021/acs.organomet.1c00313
King, A M, Wingad, R L, Pridmore, N E, Pringle, P G & Wass, D F 2021, ' Rhenium Complexes Bearing Tridentate and Bidentate Phosphinoamine Ligands in the Production of Biofuel Alcohols via the Guerbet Reaction ', Organometallics, vol. 40, no. 16, pp. 2844-2851 . https://doi.org/10.1021/acs.organomet.1c00313
We report a variety of rhenium complexes supported by bidentate and tridentate phosphinoamine ligands and their use in the formation of the advanced biofuel isobutanol from methanol and ethanol. Rhenium pincer complexes 1-3 are effective catalysts fo
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(22)
The reactions of R
Publikováno v:
Branfoot, C, Pringle, P G, Pridmore, N E, Young, T A & Wass, D F 2022, ' Heterometathesis of diphosphanes (R2P–PR2) with dichalcogenides (R′E–ER′, E = O, S, Se, Te) ', Dalton Transactions, vol. 51, no. 22, pp. 8906-8913 . https://doi.org/10.1039/d2dt01093c
The reactions of R 2P-PR 2 with R'E-ER', (where E = Se, S, O, Te) to give R 2P-ER' have been explored experimentally and computationally. The reaction of Ph 2P-PPh 2 with PhSe-SePh gives Ph 2P-SePh (1) rapidly and quantitatively. The P-P/Se-Se reacti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6da1288a1e934721b5d22a980add6a7
https://research-information.bris.ac.uk/en/publications/cb845d73-e92d-46de-bec5-635855f56bab
https://research-information.bris.ac.uk/en/publications/cb845d73-e92d-46de-bec5-635855f56bab
Publikováno v:
Branfoot, C & Pringle, P G 2021, ' Radical-initiated P,P-metathesis reactions of diphosphanes: evidence from experimental and computational studies ', Dalton Transactions, vol. 50, no. 20, pp. 7094-7104 . https://doi.org/10.1039/D1DT01013A
By combining the diphosphanes Ar2P–PAr2, where Ar = C6H5, 4-C6H4Me, 4-C6H4OMe, 3,5-C6H3(CF3)2, it has been shown that P,P-metathesis generally occurs rapidly under ambient conditions. DFT calculations have shown that the stability of unsymmetrical
The platinum(0)-diphosphine complex [Pt(CO)(L1)] (3, where L1 = 1,2-C6H4(CH2PtBu2)2) and its diphosphinite analogue [Pt(CO)(L2)] (11, where L2 = 1,2-C6H4(OPtBu2)2) act as Lewis bases in conjunction with the main group Lewis acid B(C6F5)3 to form frus
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2d2e47fe2411280a07053700117209fc
https://orca.cardiff.ac.uk/id/eprint/129642/1/KM_Pt_full_paper_corrected.pdf
https://orca.cardiff.ac.uk/id/eprint/129642/1/KM_Pt_full_paper_corrected.pdf
Publikováno v:
Hamilton, H, King, A, Sparkes, H, Pridmore, N & Wass, D 2019, ' Zirconium-Nitrogen Intermolecular Frustrated Lewis Pairs ', Inorganic Chemistry, vol. 58, no. 9, pp. 6399-6409 . https://doi.org/10.1021/acs.inorgchem.9b00569
A series of intermolecular transition metal frustrated Lewis pairs (FLPs) based on zirconocene alkoxide complexes ([Cp2Zr(OMes)]+ 1 or ([Cp*2Zr(OMes)]+ 2) with nitrogen Lewis bases (NEt3, NEtiPr2, pyridine, 2-methylpyridine, 2,6-lutidine) are reporte
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::68b227e212b4f158e4f4521c20cb1553
https://orca.cardiff.ac.uk/id/eprint/122472/1/acs.inorgchem.9b00569_PP.pdf
https://orca.cardiff.ac.uk/id/eprint/122472/1/acs.inorgchem.9b00569_PP.pdf
Publikováno v:
Chemical communications (Cambridge, England). 55(3)
The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone
Publikováno v:
Baker, A, Wass, D & Trask, R 2016, ' Novel Multi-Stage Three-Dimensional Deployment Employing Ionoprinting of Hydrogel Actuators ', MRS Advances, vol. 1, no. 58, pp. 3871-3876 . https://doi.org/10.1557/adv.2016.361
Novel multi-stage adaptive morphing of a hydrogel cube has been achieved by combining multi-metal ionoprinting and redox chemistry of iron. A demonstration of the two-stage deployment has been shown for (1) the selective opening and closing of the cu
Publikováno v:
Organometallics. 35:847-850
Zirconium-based frustrated Lewis pairs (FLPs) are active imine hydrogenation catalysts under mild conditions. Complexes of the type [CpR2ZrOMes][B(C6F5)4] utilize the imine substrate itself as the Lewis base component of the FLP. Catalyst performance
Autor:
Matthew Everett, Duncan F. Wass
Publikováno v:
Everett, M & Wass, D F 2017, ' Highly productive CO 2 hydrogenation to methanol – a tandem catalytic approach via amide intermediates ', Chemical Communications, vol. 53, no. 68, pp. 9502-9504 . https://doi.org/10.1039/c7cc04613h
A new system for CO2 reduction to methanol has been demonstrated using homogeneous ruthenium catalysts with a range of amine auxiliaries. Modification of this amine has a profound effect on the yield and selectivity of the reaction. A TON of 8900 and