Zobrazeno 1 - 10
of 115
pro vyhledávání: '"Duff Reaction"'
Autor:
Erik Ortiz-Blanco, Maritza Mendoza-de la Cruz, Ricardo Tovar-Miranda, Gabriela Alejandra Sosa-Ortiz, Tomás Guerrero
Publikováno v:
Results in Chemistry, Vol 5, Iss , Pp 100932- (2023)
The formylation of aromatic substrates is an important reaction in organic chemistry. Indeed, several protocols have been published to afford aromatic aldehydes, which are important precursors in materials and medicinal chemistry. One useful, neverth
Externí odkaz:
https://doaj.org/article/a913b37b63b24292862cc64466ab5c0c
Publikováno v:
Molecules, Vol 26, Iss 24, p 7482 (2021)
More efficient and preferably more convenient and greener synthetic solutions in coumarin scaffold functionalization are in steady demand. The Duff ortho-formylation of unsubstituted umbelliferone was revised in this study. The reaction conditions we
Externí odkaz:
https://doaj.org/article/0b47a2eb722e41e6b7835a30443189a0
Akademický článek
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Publikováno v:
Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 7, Iss 1, Pp 87-96 (2020)
Volume: 7, Issue: 1 87-96
Journal of the Turkish Chemical Society Section A: Chemistry
Volume: 7, Issue: 1 87-96
Journal of the Turkish Chemical Society Section A: Chemistry
In this study, numerous coumarin compounds were synthesized by Pechmann and Knoevenagel methods, and the substitution of the formyl group was provided by the Duff reaction. The FTIR spectra and melting points of the synthesized compounds were compare
Publikováno v:
Organic Process Research & Development. 25:1022-1027
We reported herein an efficient and practical method to access 1,7′-dimethyl-2′-propyl-2,5′-bi(1H-benzimidazole) 1, a key intermediate for the synthesis of telmisartan. The synthetic route was base...
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Publikováno v:
Chemistry of Natural Compounds. 56:420-422
7-Hydroxy-8-methyl-4'-methoxy-6-formylisoflavone was synthesized from the 6-aminomethyl derivative of 7-hydroxychromone under modified Duff reaction conditions and underwent heterocyclization to form linear furo- and pyranochromones.
Publikováno v:
Chemistry of Natural Compounds. 54:1064-1067
Furo[2,3-h]chromone and pyrano[2′,3′:5,6]chromeno[4,3-b]pyridine derivatives were synthesized from 7-hydroxy-8-formylisoflavones, which were prepared from natural isoflavones using a Duff reaction, via reactions with bromoacetophenones and ethyl
Publikováno v:
Natural Product Research. 33:1897-1902
The first direct synthesis of 3-N-methyl-9-formylcytisine via electrophylic formylation is described. It is established, that Vilsmeier-Haack and Gatterman variants of this reaction are unsuccessfu...