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pro vyhledávání: '"Duanteng Chen"'
Publikováno v:
Advanced Synthesis & Catalysis. 353:3373-3379
An efficient and clean method to construct CC bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (
Autor:
Seok Hwan Kim, Isabelle Thome, Duanteng Chen, Astrid Beyer, Julien Bonnamour, Carsten Bolm, Sukbok Chang, Yu Yuan, Erik Zuidema
Publikováno v:
Advanced Synthesis & Catalysis. 352:2892-2898
Potassium hydroxide (KOH) in dimethyl sulfoxide (DMSO) forms a superbasic medium that allows one to access cross-coupling products from reactions between aryl halides with various sulfur-, oxygen- and nitrogen-based nucleophiles under transition meta
Publikováno v:
ChemInform. 43
Oxidative coupling of benzylic alcohols (II) and (IV) with acetanilides (I) proceeds readily in the system tert-butyl hydroperoxide—TfOH—Pd(O-Ac)2 to afford o-aroylanilides (III) and (V), resp., in moderate to good yields.
Autor:
Seok Hwan Kim, Isabelle Thome, Duanteng Chen, Carsten Bolm, Astrid Beyer, Julien Bonnamour, Erik Zuidema, Sukbok Chang, Yu Yuan
Publikováno v:
ChemInform. 42
Reaction of O-, N- and S-nucleophiles with various aryl halides proceeds smoothly in the superbasic system KOH—DMSO.