Zobrazeno 1 - 10
of 77
pro vyhledávání: '"Dowd–Beckwith ring-expansion reaction"'
Autor:
O. Crosby
Publikováno v:
Catalysis from A to Z.
Autor:
Shun-ichi Hirose, Sari Hamamoto, Nobuhiro Kihara, Yoshinori Uzawa, Akane Fujioka, Makoto Sato, Ryo Iwasaki, Yuji Mitsuhashi, Natsumi Shirai, Erika Goudo
Publikováno v:
Tetrahedron Letters. 57:2563-2566
Anilines were protected as 2-(phenylseleno)ethanesulfonanilide (SeES anilide) via sulfonylation by 2-chlorosulfonyl chloride followed by the conjugate addition of benzeneselenol. The SeES anilide was deprotected by radical reduction using tributyltin
Autor:
Xiaoqing Zhu, Fengrui Liu
Publikováno v:
European Journal of Organic Chemistry. 2014:7329-7332
The reaction constant (ρ) from the kinetics for hydride transfer from a carbanion (XH–) to 9-arylxanthylium ions (9-GPhXn+) in CH3CN was unusually negative. Thermodynamic analysis indicated that ρ for the simple hydride transfers (only involved w
The course of the reaction of 2-propargyl-2-(2-carboethoxyvinyl)cyclohexanone with tributyltin hydride and AIBN either neat or in benzene solution is discussed. The structure of the spirocyclic major product is shown to differ from that previously su
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aac8ddf93f6af1b2d1a6f4e0ebd5a2cd
https://doi.org/10.1016/s0040-4020(00)00848-6
https://doi.org/10.1016/s0040-4020(00)00848-6
Publikováno v:
Journal of Porphyrins and Phthalocyanines. 16:616-625
The reaction of tetrapropylporphycenatocobalt(III) with tributyltin hydride generates a cobalt(III)–hydride porphycene detectable by UV-vis spectroscopy under diluted conditions, whereas it is impossible to characterize hydride species of cobalt po
Publikováno v:
European Journal of Organic Chemistry. 2010:1333-1338
A series of benzo-fused tricyclic β-lactams, most of them phosphonobenzocarbacephems, were prepared in a straightforward way starting from phosphonoazadienes. In this paper, the synthetic route including a Staudinger reaction towards the β-lactams,
Publikováno v:
Bulletin of the Korean Chemical Society. 29:2379-2382
Sodium cyanoaluminum hydride (SCAH) was prepared by the reaction of aluminum hydride and sodium cyanide in tetrahydrofuran at room temperature, and the approximate rates and stoichiometry of the reaction with selected organic compounds containing rep
Publikováno v:
Journal of Applied Chemistry. 14:257-261
Sodium hydride and boron trichloride react to form nearly stoicheiometric amounts of diborane in the presence of anhydrous aluminium chloride and aromatic solvents such as benzene. The sodium chloride by-product, which apparently prevents reaction of
Autor:
Diego Ardura, Tomás L. Sordo
Publikováno v:
The Journal of Organic Chemistry. 70:9417-9423
[Reaction: see text]. The evolution of the primary radicals formed by addition of AIBN/HSnBu3 to methyl 1-(3-iodopropyl)-5-oxocyclopentanecarboxylate, methyl (1R,2R)-1-(3-iodopropyl)-2-methyl-5-oxocyclopentanecarboxylate, and methyl (1R,2S)-1-(3-iodo
Autor:
Chung K. Chu, Youhoon Chong
Publikováno v:
Carbohydrate Research. 337:397-402
An efficient and practical route for the large-scale synthesis of 2-deoxy-L-erythro-pentose (2-deoxy-L-ribose) starting from L-arabinose was developed using Barton-type free-radical deoxygenation reaction as a key step. The radical precursor, a pheno