Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Douglas D. Wick"'
Autor:
Karen I. Goldberg, Stefan Reinartz, Michael P. Jensen, Joseph L. Templeton, Douglas D. Wick, Peter S. White
Publikováno v:
Journal of the American Chemical Society. 125:8614-8624
Reductive elimination of methane occurs upon solution thermolysis of kappa(3)-Tp(Me)2Pt(IV)(CH(3))(2)H (1, Tp(Me)2 = hydridotris(3,5-dimethylpyrazolyl)borate). The platinum product of this reaction is determined by the solvent. C-D bond activation oc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e6b9a163cbcc56377e7aee07ebeb33b
https://doi.org/10.1021/ja028477t
https://doi.org/10.1021/ja028477t
Publikováno v:
Journal of the American Chemical Society. 123:7257-7270
Experiments are described that provide indirect evidence for the involvement of alkane sigma-complexes in oxidative addition/reductive elimination reactions of Tp'Rh(L)(R)H complexes (Tp' = tris-3,5-dimethylpyrazolylborate, L = CNCH(2)CMe(3)). Reduct
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::039857e1e97dca532d1c0a4306df348b
https://doi.org/10.1021/ja003944x
https://doi.org/10.1021/ja003944x
Publikováno v:
Journal of the American Chemical Society. 121:3974-3983
Two sets of experiments are described that provide indirect evidence for the involvement of alkane σ-complexes in oxidative addition/reductive elimination reactions of Tp‘Rh(L)(R)H complexes (Tp‘ = tris-3,5-dimethylpyrazolylborate, L = CNCH2CMe3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8d9426406f8ac85860be4ad6a4854709
https://doi.org/10.1021/ja9841815
https://doi.org/10.1021/ja9841815
Autor:
Douglas D. Wick, William D. Jones
Publikováno v:
Organometallics. 18:495-505
Reaction of the complex Tp‘Rh(CNneo)(CHCH2)Cl (neo = CH2CMe3, Tp‘ = hydridotris(3,5-dimethylpyrazolyl)borate) with Cp2ZrH2 leads to the formation of Tp‘Rh(CNneo)(CHCH2)H. This complex is also formed upon photolysis of a solution of Tp‘Rh(CNne
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7951d316b62110b628a5dada8a8ab631
https://doi.org/10.1021/om9808211
https://doi.org/10.1021/om9808211
Publikováno v:
Organometallics. 17:4484-4492
Generation of the 16-electron fragment {[HB(3,5-dimethylpyrazolyl)3]Rh(CNCH2CMe3)} (Tp‘RhL) in the presence of cyclopropane results in C−H activation of the hydrocarbon. The cyclopropyl hydride complex rearranges in benzene solvent to the metalla
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a64d5ff05f56fd5154cc97f5295dcd98
https://doi.org/10.1021/om971066e
https://doi.org/10.1021/om971066e
Autor:
Douglas D. Wick, William D. Jones
Publikováno v:
Inorganic Chemistry. 36:2723-2729
A series of complexes of the type Tp'Rh(CNCH(2)CMe(3))(R)Cl, where R = CH(3), CD(3), n-propyl, isopropyl, cyclopropyl, and vinyl and Tp' = tris(3,5-dimethylpyrazolyl)borate have been synthesized and fully characterized. The complexes are prepared by
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::37443ded82cb057787a27c61310f2c06
https://doi.org/10.1021/ic961337y
https://doi.org/10.1021/ic961337y
Publikováno v:
Inorganic chemistry. 48(4)
The platinum(IV) hydride complexes Tp(Me(2))PtR(2)H (Tp(Me(2)) = hydridotris(3,5-dimethylpyrazolyl)borate, R = Me (1a), Ph (1b)) react with molecular oxygen to form platinum(IV) hydroperoxide complexes Tp(Me(2))PtR(2)OOH (R = Me (2a) and Ph (2b), res
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c0d22d12308c852c77e6a14647d94021
https://pubmed.ncbi.nlm.nih.gov/19159315
https://pubmed.ncbi.nlm.nih.gov/19159315
Publikováno v:
ChemInform. 36
The rearrangements of alkyl deuteride complexes are monitored and a kinetic model used to extract the rate constants for the fundamental processes involving the unseen alkane σ-complexes. Isotope effects for C-H and C-D bond formation and cleavage h
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::190b5b310ddb576d03ed45c0f1048ef8
https://doi.org/10.1002/chin.200509260
https://doi.org/10.1002/chin.200509260
Publikováno v:
ACS Symposium Series ISBN: 9780841238497
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d1ab30f778fef1c4b76990e2c0b49c89
https://doi.org/10.1021/bk-2004-0885.ch003
https://doi.org/10.1021/bk-2004-0885.ch003
Insertion of Dioxygen into a Platinum−Hydride Bond to Form a Novel Dialkylhydroperoxo Pt(IV) Complex
Autor:
Douglas D. Wick, Karen I. Goldberg
Publikováno v:
Journal of the American Chemical Society. 121:11900-11901
The selective catalytic oxidation of alkanes using inexpensive and environmentally friendly oxidants is of immense interest to the chemical community and of great potential benefit to the world economy and ecology. Since the earliest reports that the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::158d7e784e71d7efc75bed2f8008539a
https://doi.org/10.1021/ja992618i
https://doi.org/10.1021/ja992618i