Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Dorota Greszta"'
Autor:
Stephen V. Arehart, Michael J. Ziegler, Krzysztof Matyjaszewski, Dorota Greszta, Tadeusz Pakula
Publikováno v:
Journal of Physical Organic Chemistry. 13:775-786
Gradient copolymers, in which the instantaneous composition varies continuously along each chain, are discussed in terms of theoretical background, significance and examples from the literature. The specific focus is the use of atom transfer radical
Autor:
S. Grimaldi, Jeremy J. Hastings, Dorota Greszta, Andrew J. Shooter, D. Gigmes, Philippe Jules Teyssie, Robert Jerome, Krzysztof Matyjaszewski, Christina B. Jasieczek, Claude Granel, Paul Tordo, David M. Haddleton
Publikováno v:
Macromolecules. 31:7133-7141
Results of methyl methacrylate (MMA) and vinyl acetate (VOAc) polymerization using the Al(iBu)3/2,2‘-bipyridine/TEMPO initiating system at room temperature failed to confirm the “living” radical mechanism reported earlier. Several species appar
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 35:1857-1861
Publikováno v:
Macromolecules. 29:7661-7670
The polymerization of styrene in the presence of a stable radical, TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy), has been simulated using a Predici simulations package. On the basis of the experime...
Autor:
Krzysztof Matyjaszewski, Scott G. Gaynor, Dorota Greszta, Daniela Mardare, Takeo Shigemoto, Jin-Shan Wang
Publikováno v:
Macromolecular Symposia. 95:217-231
Well defined polymers can be produced by radical polymerization using three different approaches: degenerative, transfer, reversible homolytic cleavage of covalent species, and reversible homolytic cleavage of persistent radicals. The first method re
Publikováno v:
Journal of Physical Organic Chemistry. 8:306-315
Radical polymerizations cannot truly be ‘living’ because of the inevitable termination between growing radicals. However, relatively good control of molecular weights, polydispersities and terminal functionalities can be achieved by using either
Publikováno v:
Macromolecules. 28:59-72
Monomodal polysilylenes with relatively narrow molecular weight distributions (M sub w/M sub n) < 1.5) have been prepared by the reductive coupling of methylphenyldichlorosilane and di-n-hexyldichlorosilane with alkali metals in toluene in the presen
Publikováno v:
Macromolecules. 27:638-644
Possibility of the synthesis of well-defined polymers by radical polymerization is discussed. Kinetic analysis demonstrates that the preparation of polymers with controlled macromolecular structure in a 'living' radical process requires low stationar
Publikováno v:
Journal of Macromolecular Science, Part A. 31:1561-1578
Various methods which lead to the control of molecular weight and polydispersities, and which allow for the preparation of block copolymers by radical polymerization are discussed. Thermal polymerizationof styrenes in the presence of stable radicals,
Publikováno v:
Macromolecules. 26:6231-6236
Bis(γ-ethoxypropyl)dichlorosilane was synthetized by hydrosilylation of dichlorosilane. Polymerization yielded monomodal high molecular weight poly[bis(γ-ethoxypropyl)silylene] (PDEPS). PDEPS is soluble in alcohols with longer alkyl groups end acet