Role of Li Concentration and the SEI Layer in Enabling High Performance Li Metal Electrodes Using a Phosphonium Bis(fluorosulfonyl)imide Ionic Liquid

Autor: Serguei Zavorine, Matthias Hilder, Douglas R. MacFarlane, Gaetan M. A. Girard, Maria Forsyth, Patrick C. Howlett, Michael Moser, Kristina Whitbread, Donato Nucciarone

Publikováno v: The Journal of Physical Chemistry C. 121:21087-21095

In this study the performance of the lithium (Li) anode is characterized in two alternative ionic liquid electrolytes: (i) a solution of 0.5 mol·kg–1 of lithium bis(fluorosulfonyl)imide (LiFSI) in trimethyl(isobutyl)phosphonium FSI (P111i4FSI) and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8c48444790bac408d95b7669d59f5a72
https://doi.org/10.1021/acs.jpcc.7b01929

Spectroscopic Characterization of the SEI Layer Formed on Lithium Metal Electrodes in Phosphonium Bis(fluorosulfonyl)imide Ionic Liquid Electrolytes

Autor: Nicolas Dupré, Michael Moser, Maria Forsyth, Kristina Whitbread, Dominique Guyomard, Donato Nucciarone, Serguei Zavorine, Patrick C. Howlett, Gaetan M. A. Girard, Matthias Hilder, Douglas R. MacFarlane

Publikováno v: ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2018, 10 (7), pp.6719-6729. ⟨10.1021/acsami.7b18183⟩

The chemical composition of the solid electrolyte interphase (SEI) layer formed on the surface of lithium metal electrodes cycled in phosphonium bis(fluorosulfonyl)imide ionic liquid (IL) electrolytes are characterized by magic angle spinning nuclear

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d599ce2eef6082be00c427f64b247346
https://pubmed.ncbi.nlm.nih.gov/29377667

Electrochemical and physicochemical properties of small phosphonium cation ionic liquid electrolytes with high lithium salt content

Autor: Patrick C. Howlett, Maria Forsyth, Kristina Whitbread, Serguei Zavorine, Donato Nucciarone, Matthias Hilder, Michael Moser, Douglas R. MacFarlane, Gaetan M. A. Girard, Haijin Zhu

Publikováno v: Physical chemistry chemical physics : PCCP. 17(14)

Electrolytes of a room temperature ionic liquid (RTIL), trimethyl(isobutyl)phosphonium (P111i4) bis(fluorosulfonyl)imide (FSI) with a wide range of lithium bis(fluorosulfonyl)imide (LiFSI) salt concentrations (up to 3.8 mol kg(-1) of salt in the RTIL

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::484a0e45acc92515c8c70be7fb0c084d
https://pubmed.ncbi.nlm.nih.gov/25820549

A Phosphonium Bis(fluorosulfonyl)Imide-Based Ionic Liquid Electrolyte for Lithium Batteries: Tailoring Composition and Performance

Autor: Gaetan Marc-Antoine Girard, Matthias Hilder, Kristina Whitbread, Donato Nucciarone, Serguei Zavorine, Michael Moser, Maria Forsyth, Douglas R MacFarlane, Patrick C Howlett

Publikováno v: ECS Meeting Abstracts. :95-95

The electrolyte is one of the key components of an energy storage device required to achieve high reliability and safety as well as high energy density. Lithium batteries have become one of the most common technologies for portable electronics and ar

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ef1c3a6fac442d46ad417809188c1fc4
https://doi.org/10.1149/ma2015-01/1/95

Chemical transformations on phosphido-bridged clusters. Methyne, methylene transfer, and ketene forming reactions involving the .mu.-methylene cluster Ru3(CO)7(.mu.-CH2)[.mu.3-.eta.3-CH2:C:C(CHMe2)](.mu.-PPh2). X-ray structures of (.mu.-H)Ru3(CO)7[.mu.3-.eta.4-CH:C(CHMe2)C:CH2](.mu.-PPh2) and Ru3(CO)6(.mu.-CO)[.mu.3-.eta.4-CH2:C(CHMe2)C:CH2](PPh3)(.mu.-PPh2)

Autor: Donato Nucciarone, Nicholas J. Taylor, Arthur J. Carty, Antonio Tiripicchio, Marisa Tiripicchio Camellini, Enrico Sappa

Publikováno v: Organometallics. 7:118-126

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dc8aa8cd1d5839fe40b130828f51cca9
https://doi.org/10.1021/om00091a020