Zobrazeno 1 - 10
of 69
pro vyhledávání: '"Donald W, Setser"'
Autor:
George L. Heard, Mallory M. Rothrock, Blanton R. Gillespie, Bert E. Holmes, Anthony J. Ranieri, Melinda K. Schueneman, Donald W. Setser, Timothy M. Brown
Publikováno v:
The Journal of Physical Chemistry A. 123:8776-8786
Chemical activation experiments and computational methods have been used to study the unimolecular reactions of C2H5CH2Br and C2D5CHFBr with 90 and 93 kcal mol–1 of vibrational energy, respectively...
Autor:
Chaitanya A Patel, Blanton R. Gillespie, Bert E. Holmes, George L. Heard, Donald W. Setser, Mallory M. Rothrock
Publikováno v:
The Journal of Physical Chemistry A. 123:2621-2633
The gas-phase unimolecular reactions of C2D5CHFCl molecules with 94 kcal mol-1 of vibrational energy have been studied by the chemical-activation experimental technique and by electronic-structure computations. Products from the reaction of C2D5CHFCl
Publikováno v:
Chemical Physics. 555:111404
Reactions of OH and OD radicals with C2H5SH and (C2H5)2S were studied by Fourier-transform infrared emission spectroscopy of the water product molecules from a fast-flow reactor. Vibrational excitation of the H2O, HOD and D2O product molecules was de
Autor:
Matthew J. Nestler, Timothy M. Brown, Bert E. Holmes, George L. Heard, Donald W. Setser, Blanton R. Gillespie, Caleb A Smith
Publikováno v:
The Journal of Physical Chemistry A. 122:8446-8457
The five unimolecular HX and DX (X = F, Cl) elimination pathways of CD2ClCHFCl* were examined using a chemical activation technique; the molecules were generated with 92 kcal mol–1 of vibrational energy in a room-temperature bath gas by a combinati
Autor:
Donald W. Setser, N. I. Butkovskaya
Publikováno v:
The Journal of Physical Chemistry A. 122:3735-3746
Reactions of OH and OD radicals with NH2CHO and ND2CHO were studied by Fourier transform infrared emission spectroscopy of the product molecules from a fast-flow reactor at 298 K. Vibrational distributions of the HOD and H2O molecules from the primar
Publikováno v:
The Journal of Physical Chemistry A. 121:8746-8756
The recombination of CF3 and CHF2 radicals in a room-temperature bath gas was used to prepare vibrationally excited CF3CHF2* molecules with 101 kcal mol–1 of vibrational energy. The subsequent 1,2-H atom transfer and 1,1-HF and 1,2-HF elimination r
Publikováno v:
The Journal of Physical Chemistry A. 120:9357-9362
The recombination of ·CHF2 radicals in a room-temperature bath gas was used to generate CHF2CHF2* (where * indicates vibrational excitation) molecules with 96 kcal mol–1 of vibrational energy. The CHF2CHF2* molecules decompose by four-centered 1,2
Autor:
Timothy M, Brown, Blanton R, Gillespie, Mallory M, Rothrock, Anthony J, Ranieri, Melinda K, Schueneman, George L, Heard, Donald W, Setser, Bert E, Holmes
Publikováno v:
The journal of physical chemistry. A. 123(41)
Chemical activation experiments and computational methods have been used to study the unimolecular reactions of C
Autor:
Donald W. Setser, Caleb A Smith, George L. Heard, Bert E. Holmes, Allie C. Larkin, Matthew J. Nestler
Publikováno v:
The Journal of Physical Chemistry A. 120:8244-8253
Chemically activated C2D5CHCl2 molecules were generated with 88 kcal mol–1 of vibrational energy by the recombination of C2D5 and CHCl2 radicals in a room temperature bath gas. The competing 2,1-DCl and 1,1-HCl unimolecular reactions were identifie
Autor:
Leah Wormack, Donald W. Setser, Corey E. McClintock, Meghan E. McGreal, Bert E. Holmes, George L. Heard
Publikováno v:
The Journal of Physical Chemistry A. 119:3887-3896
The recombination of CHF2 and C2D5 radicals was used to produce CD3CD2CHF2* molecules with 96 kcal mol(-1) of vibrational energy in a room temperature bath gas. The formation of CD3CD═CHF and CD3CD═CDF was used to identify the 1,2-DF and 1,1-HF u