Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Donald V. Scaltrito"'
Autor:
David W. Thompson, Donald V. Scaltrito, Arnold L. Rheingold, Gerald J. Meyer, Reza A. Ghiladi, Ryan M. Kretzer, Kin Chung Lam, Estelle L. Lebeau, Kenneth D. Karlin
Publikováno v:
Inorganic Chemistry. 42:5211-5218
We present here the synthesis, characterization, and flash photolysis study of [(F(8)TPP)Fe(II)(CO)(THF)] (1) [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]. Complex 1 crystallizes from THF/heptane solvent system as a tris-THF solvate, [(F(
Publikováno v:
Coordination Chemistry Reviews. 208:243-266
Cuprous bis-phenanthroline compounds possess metal-to-ligand charge transfer, MLCT, excited states. Phenanthroline ligands coordinated to Cu(I) that are disubstituted in the 2- and 9-positions with alkyl or aryl groups, abbreviated CuI(phen′)2+, ha
Autor:
and Donald V. Scaltrito, Matthew L. Peterson, Stuart W. Staley, Carl A. Morales, Jeffrey T. Strnad, Thomas P. Markotan
Publikováno v:
The Journal of Organic Chemistry. 64:9067-9076
The single-crystal X-ray structures of 6-(4-(dimethylamino)phenyl)-6-methylfulvene (2) and of two polymorphs of 6-(4-(dimethylamino)phenyl)-6-phenylfulvene (3(P21/c) and 3(Pca21)) have been determined and the structures of a series of 6-arylfulvenes
Publikováno v:
Journal of the American Chemical Society. 125(39)
The observation and fast time-scale kinetic determination of a primary dioxygen-copper interaction have been studied. The ability to photorelease carbon monoxide from [Cu(I)(tmpa)(CO)](+) in mixtures of CO and O(2) in tetrahydrofuran (THF) between 18
Autor:
† Eun-il Kim, David W. Thompson, Christiana Xin Zhang, Donald V. Scaltrito, Hong-Chang Liang, Kenneth D. Karlin, Gerald J. Meyer, Brett M. Showalter, John P. Toscano, H. C. Fry, Ryan M. Kretzer
Publikováno v:
Inorganic chemistry. 40(18)
Pulsed light excitation of [CuI(TMPA)(CO)]+ in organic solvents at room-temperature results in rapid, k > 108 s-1, release of carbon monoxide to yield the solvento complex, [CuI(TMPA)(S)]+. The dynamics of this process and the subsequent rebinding of
Autor:
Yi-Zhen Hu, Randolph P. Thummel, Elvira C. Riesgo, Gerald J. Meyer, Frederic Bouvier, Donald V. Scaltrito
Publikováno v:
Inorganic chemistry. 40(14)
The Friedlander condensation was employed to synthesize two series of 3,3'-polymethylene bridged ligands, L, based on 2-(2'-pyridyl)-benzo[h]quinoline and 2,2'-bibenzo[h]quinoline (BHQ) along with the fully aromatic naphtho[1,2-b]-1,10-phenanthroline
Publikováno v:
Inorganic chemistry. 39(17)
The coordination compounds [Cu(bpy-MV2+)(PPh3)2](PF6)3, where bpy-MV2+ is the 1-(4-(4'-methyl-2,2'-bipyridin-4-yl)butyl)-1'-methyl-4, 4'-bipyridinediium(2+) cation, and [Cu(dmb)(PPh3)2](PF6), where dmb is 4,4'-dimethyl-2,2'-bipyridine, have been prep
Publikováno v:
ChemInform. 31
Cuprous bis-phenanthroline compounds possess metal-to-ligand charge transfer, MLCT, excited states. Phenanthroline ligands coordinated to Cu(I) that are disubstituted in the 2- and 9-positions with alkyl or aryl groups, abbreviated CuI(phen′)2+, ha