Zobrazeno 1 - 10
of 121
pro vyhledávání: '"Donald R. Arnold"'
Autor:
Donald R. Arnold, Dino Mangion
Publikováno v:
Accounts of Chemical Research. 35:297-304
The photochemical nucleophile-olefin combination, aromatic substitution (photo-NOCAS) reaction has been a cornerstone of research in our laboratory for several years. In this Account we present an overview of the mechanistic exploration and rationali
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :48-60
The photochemical reactions of 1,2,4,5-tetracyanobenzene (1), 1,4-dicyanobenzene (2) and 1,4-dicyanonaphthalene (3) with tetramethylallene (4) and 1,1-dimethylallene (5) in acetonitrile–methanol solution have been investigated. Both 1 and 2 give 1
Publikováno v:
Organic Letters. 3:45-48
[figure: see text] A series of 1-arylcyclohexenes have been deconjugated to the corresponding 3-arylcyclohexenes via a photosensitized electron-transfer reaction. The introduction of substituents on the aryl group has provided insight into the underl
Autor:
Dino Mangion, Donald R. Arnold
Publikováno v:
Canadian Journal of Chemistry. 77:1655-1670
The photochemical reactivity of a series of 4-halobenzonitriles and 4-haloanisoles with 1,1-diphenylethene in a nucleophilic solvent (methanol) has been investigated. Analysis of the photochemical reactions involving the 4-halobenzonitriles revealed
Publikováno v:
Canadian Journal of Chemistry. 76:1817-1826
The cleavage reactions of the 1-butene and 4,4-dimethyl-1-pentene molecules and their cations, to form neutral and charged hydrocarbon products, are investigated using hybrid Hartree-Fock/density functional theory. In comparison with previous theoret
Autor:
Donald R. Arnold, Kimberly A. McManus
Publikováno v:
Canadian Journal of Chemistry. 76:1238-1248
The photochemical nucleophile-olefin combination, aromatic substitution (photo-NOCAS) reaction of methanol, 7-methyl-3-methylene-1,6-octadiene ( β-myrcene, 1), and 1,4-dicyanobenzene yields five 1:1:1 adducts:cis-2-(4-cyanophenyl)-4-(1-methoxy-1-met
Autor:
Donald R. Arnold, H. J. P. de Lijser
Publikováno v:
The Journal of Physical Chemistry A. 102:5592-5598
The additions of cations, radicals, and radical cations to nitriles, in particular acetonitrile, have been investigated. The literature reports examples of all of these reactions and on the basis o...
Publikováno v:
Canadian Journal of Chemistry. 76:1817-1826
The cleavage reactions of the 1-butene and 4,4-dimethyl-1-pentene molecules and their cations, to form neutral and charged hydrocarbon products, are investigated using hybrid Hartree-Fock/density functional theory. In comparison with previous theoret
Autor:
Mary S.W. Chan, Donald R. Arnold
Publikováno v:
Canadian Journal of Chemistry. 75:1810-1819
The scope of the photochemical nucleophile–olefin combination, aromatic substitution (photo-NOCAS) reaction has been extended to include fluoride anion as the nucleophile. The 4-cyanophenyl substituted fluoroalkanes were obtained in moderate yields
Publikováno v:
Canadian Journal of Chemistry. 75:1055-1075
The scope of the photochemical nucleophile–olefin combination, aromatic substitution (photo-NOCAS) reaction has been extended to include cyanide anion as the nucleophile. Highest yields of adducts were obtained when the alkene or diene has an oxida