Zobrazeno 1 - 10
of 39
pro vyhledávání: '"Donald Pilipovich"'
Publikováno v:
Inorganic Chemistry. 22:1355-1358
Publikováno v:
Chemical Physics Letters. 50:301-305
The reaction of iodobistrifluoromethylphosphine, P(CF 3 ) 2 I, with atomic fluorine was studied by fast-flow ESR methods. The initial stage of the reaction is the abstraction of I by F, to form IF with a bimolecular rate constant of (1.0 ± 0.3) × 1
Publikováno v:
Chemical Physics Letters. 35:349-352
HCl (υ = 1) collisional relaxation rates have been measured for a number of polyatomic collision partners. The data suggest that for the polyatomic hydride (RH) species tested, the energy transfer proceeds via a vibration to vibration mechanism. The
Publikováno v:
Chemical Physics Letters. 35:345-348
The reactions of chlorine with hydrides of elements in groups IV, V, and VI have been investigated with respect to their potential as sources for HCl chemical lasers. For these systems, chain reactions involving Cl 2 should contribute in some measure
Publikováno v:
Inorganic Chemistry. 22:810-814
Publikováno v:
Chemical Physics Letters. 33:347-350
The reaction rate constant of the addition of atomic fluorine to excess PF 3 was determined by fast flow ESR measurements to be (8.6 ± 0.6) × 10 12 cm 3 mole −1 s −1 at 300 K. The stoichiometry of the overall reaction of F with PF 3 was 2:1. Fi
Publikováno v:
Inorganic Chemistry. 11:1679-1682
Publikováno v:
Inorganic Chemistry. 11:2201-2205
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 27:931-936
The infrared spectrum of matrix isolated BrF 3 has been recorded. All six fundamental vibrations expected for a T -shaped molecule of symmetry C 2 v were observed. A modified valence force field and some thermodynamic properties have been computed fo
Publikováno v:
Inorganic Chemistry. 11:2189-2192