Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Donald G. Hesse"'
Publikováno v:
Thermochimica Acta. 313:101-110
The sublimation enthalpies of 17 hydrocarbons are obtained by combining the technique of correlation gas chromatography (CGC), to evaluate vaporization enthalpies at 298.15 K, and differential scanning calorimetry (DSC) to measure fusion enthalpies.
Autor:
Donald G. Hesse, Klaus Rakus, Sergej P. Verevkin, Sarah Hosseini, Christoph Rüchardt, G. David Mendenhall, Joel F. Liebman, James S. Chickos, Hans Dieter Beckhaus
Publikováno v:
The Journal of Chemical Thermodynamics. 27:693-705
Measurements of the molar enthalpy of vaporization Δ vap H m at the temperature T = 298.15 K are reported for 14 liquids and 6 solids each containing one or more quaternary carbon atoms, by the methods of transpiration, head-space analysis, or gas c
Publikováno v:
Thermochimica Acta. 249:41-62
A technique is described for determining vaporization enthalpies Δg1Hm(298 K) of organic compounds by high resolution gas chromatography. The technique correlates changes in net retention times of compounds whose Δg1Hm(298 K) are known with those o
Publikováno v:
Structural Chemistry. 4:271-278
The estimation methods commonly used to correct phase change enthalpies to the standard state are compared where possible to experimental measurements. Heat capacity corrections for liquid-gas equilibria are found to correlate with molecular structur
Publikováno v:
Structural Chemistry. 4:261-269
A group additivity method is described which provides heat capacity estimates of the condensed phase. The data base consists of 810 liquids and 446 solids. Group values for carbon in various common substitution and hybridization states and for 47 fun
Publikováno v:
ChemInform. 22
Publikováno v:
The Journal of Organic Chemistry. 56:927-938
A group additivity method recently reported for estimating fusion entropies and fusion enthalpies of hydrocarbons is expanded to include both mono- and multisubstituted derivatives as well. The parameters are derived from experimental fusion enthalpi
Autor:
Donald G. Hesse, James S. Chickos
Publikováno v:
Structural Chemistry. 2:33-40
Vapor pressures, fusion (δHfus), and sublimation (δHs) enthalpies are reported ford, dl-2,3-dibromobutane-1,4-diol, andd,dl-dimethyl 2,3-diacetyltartrate. Values of 8.1, 7.04, 6.9, and 6.6 kcal/mol for δHfus were measured by differential scanning
Publikováno v:
The Journal of Organic Chemistry. 55:3833-3840
A group additivity method for estimating fusion entropies and fusion enthalpies is described. The method is based on experimental fusion enthalpies of 191 hydrocarbons. Group values are provided for most structural environments. Applications of the t
Publikováno v:
The Journal of Organic Chemistry. 54:5250-5256
A simple method of estimating vaporization enthalpies of hydrocarbon derivatives containing one or more functional groups is described. The relationship previously reported for monosubstituted derivatives has been modified to included additional stru