Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Donald E. Wall"'
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 331:2751-2760
Publikováno v:
Radiochimica Acta. 108:409-414
Technetium-99 is a long-lived fission product present in nuclear wastes, found mainly as Tc(VII) and Tc(IV) in the environment. The quantification of the equilibrium constants for the formation of Tc(IV) aqueous complexes has been limited to carboxyl
Autor:
T. Gannon Parker, Lindsey M. Lecrivain, Cecilia Eiroa-Lledo, Donald E. Wall, Nathalie A. Wall
Publikováno v:
Radiochimica Acta. 108:443-449
The suitability of perrhenate (Re(VII)) to act as an analog for pertechnetate (Tc(VII)) was tested using solvent extraction and the carrier/tracer systems 99Tc(VII)/99mTc(VII) and 185/187Re/186/188Re(VII). Perrhenate is often used as a non-radioactiv
Publikováno v:
Journal of Luminescence. 207:1-13
A proposed method for treating nuclear high level radioactive (NHLW) is to encapsulate it in a matrix made of complex oxide materials, such as pyrochlores with the general formula A2B2O7. Rare-earth hafnate pyrochlores have the potential to advance t
Autor:
Cecilia Eiroa Lledo, Nathalie A. Wall, Mitchell T. Friend, Donald E. Wall, Lindsey M. Lecrivain
Publikováno v:
Radiochimica Acta. 106:963-970
Technetium-99 is a high yield (~6% fission yield) fission product and long-lived (2.13×105 year half-life) component of nuclear waste that will be disposed of in a geological repository. Some 99Tc has been released into the environment due to nuclea
Publikováno v:
Journal of Solution Chemistry. 47:1192-1201
This work reports the experimental determination of the stability constant for the complexation of the Tc(IV) cation by $$ {\text{SO}}_{4}^{2 - } $$ at 1.0 mol·kg−1 ionic strength (NaCl) and pcH 1.51 ± 0.05, using a solvent extraction method. The
Autor:
Saehwa Chong, Brian J. Riley, Donald E. Wall, John S. McCloy, Diana Tabada, Claire L. Corkhill, Jacob A. Peterson
Publikováno v:
Journal of Nuclear Materials. 504:109-121
Immobilization of radioiodine is an important requirement for current and future nuclear fuel cycles. Iodosodalite [Na8(AlSiO4)6I2] was synthesized hydrothermally from metakaolin, NaI, and NaOH. Dried unwashed sodalite powders were used to synthesize
Autor:
Shannon M. Morley, Mathew D. King, Erin C. Finn, C. Corey Hines, Donald E. Wall, Brienne N. Seiner, Mathew S. Snow, Tere A. Eggemeyer, Sue B. Clark, Samuel S. Morrison, Lori A. Metz
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 314:2501-2506
This work describes a radiochemical separation procedure for the determination of gold (Au), platinum (Pt), tantalum (Ta), and tungsten (W) activation in the presence of fission products. Chemical separations result in a reduction in the minimum dete
Autor:
Nathalie A. Wall, Kevin P. Carney, Aaron T. Johnson, Jana K. Pfeiffer, Allen G. Oliver, Donald E. Wall, T. Gannon Parker, Sara M. Dickens, Martha R. Finck
Publikováno v:
Inorganic Chemistry. 56:13553-13561
Production of certified reference materials in support of domestic nuclear forensics programs require volatile precursors for introduction into electromagnetic isotopic separation instruments. β-Diketone chelates of tetravalent actinides are known f