Zobrazeno 1 - 10
of 63
pro vyhledávání: '"Dmitry V. Peryshkov"'
Publikováno v:
Inorganic chemistry. 61(46)
In this work, we report the reactivity of the carboranyl diphosphine, 1-P
Autor:
Corey R. Martin, Kyoung Chul Park, Gabrielle A. Leith, Jierui Yu, Abhijai Mathur, Gina R. Wilson, Gayathri B. Gange, Emily L. Barth, Richard T. Ly, Olivia M. Manley, Kelly L. Forrester, Stavros G. Karakalos, Mark D. Smith, Thomas M. Makris, Aaron K. Vannucci, Dmitry V. Peryshkov, Natalia B. Shustova
Publikováno v:
Journal of the American Chemical Society. 144(10)
Tuning metal oxidation states in metal-organic framework (MOF) nodes by switching between two discrete linker photoisomers via an external stimulus was probed for the first time. On the examples of three novel photochromic copper-based frameworks, we
Autor:
Corey R. Martin, Gayathri B. Gange, Dmitry V. Peryshkov, Kyoung Chul Park, Mark D. Smith, H. D. A. Chathumal Jayaweera, Bennett J. Eleazer, Alexey A. Popov
Publikováno v:
Inorganic chemistry. 60(22)
The synthesis of well-defined heterometallic complexes remains a frontier challenge in inorganic chemistry. We report an approach that relies on the sequential insertion of electrophilic metal fragments into electron-rich Ru-B bonds of the η2-BB-car
Autor:
Dmitry E. Royzman, Dmitry V. Peryshkov, Amanda L. Humphries, Gayathri B. Gange, Mark D. Smith
Publikováno v:
Journal of the American Chemical Society. 143(29)
We report metal-free bond activation by the carboranyl diphosphine 1-PtBu2-2-PiPr2-C2B10H10. This main group element system contains basic binding sites and possesses the ability to cycle through two-electron redox states. The reported reactions with
Publikováno v:
Tetrahedron. 75:1471-1474
Reaction of a boryl hydride pincer complex (POBOP)Ru(H)(PPh3) (POBOP = 1,7-OP(i-Pr)2-m-2-carboranyl) and BH3(SMe2) at 70 °C led to the selective formation of a pincer-supported metallaborane (POBOP)Ru(B3H8). Single crystal structure of (POBOP)Ru(B3H
Autor:
Dmitry V. Peryshkov, H. D. A. Chathumal Jayaweera, Mark D. Smith, Perry J. Pellechia, Md. Mamdudur Rahman
Publikováno v:
Chemical Science
Carbon atom functionalization via generation of carbanions is the cornerstone of carborane chemistry. In this work, we report the synthesis and structural characterization of free ortho-carboranyl [C2B10H11]−, a three-dimensional inorganic analog o
Autor:
Eric V. Bukovsky, Matthew R. Lacroix, Steven H. Strauss, Travis C. Folsom, Brian S. Newell, Matic Lozinšek, Dmitry V. Peryshkov, Yong Liu
Publikováno v:
Inorganic Chemistry. 57:14983-15000
Eight M(H2O)n(Z) salt hydrates were characterized by single-crystal X-ray diffraction (Z2– = B12F122–): M = Ca, Sr, n = 7; M = Mg, Co, Ni, Zn, n = 6; M = Ba, n = 4, 5. Weak O–H···F hydrogen bonding...
Publikováno v:
Organometallics. 37:2945-2949
We report the imido group exchange transformation upon reactions with nitriles with the formation of a new vinylimido group from the incoming nitrile and a free nitrile from the initial imido group. Preliminary studies suggest the mechanism comprises
Publikováno v:
Journal of Organometallic Chemistry. 867:208-213
The novel 2,6-bis(carborane)pyridine (C5H3N)(C2B10H11)2 ligand precursor containing two icosahedral carborane clusters attached to the pyridine ring was synthesized by the SNAr reaction between 2,6-difluoropyridine and lithiated ortho-carborane LiC2B
Publikováno v:
Comments on Inorganic Chemistry. 38:79-109
Metalated three-dimensional icosahedral boron clusters often exhibit high chemical and thermal stability relative to their simple borane counterparts thus making them a convenient object to study t...