Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Dmitry O. Khristolyubov"'
Publikováno v:
Organometallics.
Publikováno v:
Russian Chemical Reviews. 90:529-565
The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The syn
Autor:
T. V. Makhrova, A. A. Trifonov, Georgii K. Fukin, Anton V. Cherkasov, Dmitry M. Lyubov, Dmitry O. Khristolyubov
Publikováno v:
Russian Chemical Bulletin. 70:818-829
2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar2CHCOOH (1) (Ar = 5-Me-2-Me2NC6H3), was synthesized by the carboxylation of s[2-(dimethylamino)-5-methylphenyl]-methyllithium, [Ar2CH]Li(TMEDA), with gaseous CO2. The reaction of 1 with the cati
Autor:
Georgy K. Fukin, Anton V. Cherkasov, Alexander A. Trifonov, Dmitry O. Khristolyubov, Dmitry M. Lyubov
Publikováno v:
Mendeleev Communications. 31:54-57
The outcome of salt metathesis reactions between the equimolar amounts of LnCl3 and dimeric potassium diphenylmethanide {[2,2′-(4-MeC6H3NMe2)2CH]K(THF)}2 depends on the rare-earth metal ion. In the case of ScIII and YIII, the reactions afford chlor
Autor:
Dmitry O. Khristolyubov, Anton V. Cherkasov, Dmitry M. Lyubov, Georgy K. Fukin, Andrey S. Shavyrin, Alexander A. Trifonov
Publikováno v:
Inorganic Chemistry Frontiers. 7:2459-2477
Ln(II) (Ln = Yb, Sm) and Ca(II) [NCsp3N] pincer type diarylmethanido complexes [2,2′-(4-MeC6H3NMe2)2CH]2M (M = Yb (2), Sm (3), Ca (4)) coordinated by a tridentate diarylmethanido ligand were synthesized through salt metathesis reactions of {[2,2′
Autor:
Andrey S. Shavyrin, Georgy K. Fukin, Dmitry O. Khristolyubov, Alexander A. Trifonov, Anton V. Cherkasov, Dmitry M. Lyubov
Publikováno v:
Organometallics. 37:1627-1634
A series of alkali-metal alkyl complexes containing a tridentate benzhydryl ligand, [2,2′-(4-MeC6H4NMe2)2CH]Li(TMEDA) (1TMEDA), [2,2′-(4-MeC6H4NMe2)2CH]Na(THF)3 (2THF), {[2,2′-(4-MeC6H4NMe2)2CH]K(THF}2 (3THF), and [2,2′-(4-MeC6H4NMe2)2C(SiMe3