Metal-to-metal electron transfer in a cyanido-bridged {Fe

Autor: Corine, Mathonière, Dmitri, Mitcov, Evangelia, Koumousi, Daniel, Amorin-Rosario, Pierre, Dechambenoit, Sadaf, Fatima Jafri, Philippe, Sainctavit, Christophe, Cartier Dit Moulin, Loic, Toupet, Elzbieta, Trzop, Eric, Collet, Marie-Anne, Arrio, Andrei, Rogalev, Fabrice, Wilhelm, Rodolphe, Clérac

Publikováno v: Chemical communications (Cambridge, England). 58(86)

The switching properties of a cyanido-bridged Fe/Co square molecule were investigated by single-crystal X-ray diffraction and X-ray absorption spectroscopy at both Fe and Co K-edges. Combining these two techniques, a complete picture of the thermal-,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::b99c758a77fdac0cd54dbf7839c85b1d
https://pubmed.ncbi.nlm.nih.gov/36222458

Hard X-ray magnetochiral dichroism in a paramagnetic molecular 4f complex

Autor: M.S. Platunov, Fabrice Wilhelm, Andrei Rogalev, Stergios Piligkos, Christian D. Buch, Anders Døssing, Anders Reinholdt, Dmitri Mitcov

Publikováno v: 'Chemical Science ', vol: 11, pages: 8306-8311 (2020)
Chemical Science
Mitcov, D, Platunov, M, Buch, C D, Reinholdt, A, Døssing, A R, Wilhelm, F, Rogalev, A & Piligkos, S 2020, ' Hard X-ray magnetochiral dichroism in a paramagnetic molecular 4f complex ', Chemical Science, vol. 11, no. 31, pp. 8306-8311 . https://doi.org/10.1039/D0SC02709J

Magnetochiral dichroism (MΧD) originates in the coupling of local electric fields and magnetic moments in systems where a simultaneous break of space parity and time-reversal symmetries occurs. This magnetoelectric coupling, displayed by chiral magn

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d2e3011fb8bc3bf73cf9b1f717cfea2
https://epn-library.esrf.fr/flora/jsp/index_view_direct_anonymous.jsp?record=doc:PUB_ESRF:55948

[(V

Autor: Hector W L, Fraser, Emily H, Payne, Arup, Sarkar, Lucinda R B, Wilson, Dmitri, Mitcov, Gary S, Nichol, Gopalan, Rajaraman, Stergios, Piligkos, Euan K, Brechin

Publikováno v: Dalton transactions (Cambridge, England : 2003). 50(36)

Heterometallic Anderson wheels of formula [(V

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::c3fdc37b0a32cf31194576e38114203e
https://pubmed.ncbi.nlm.nih.gov/34240723

Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet† †Electronic supplementary information (ESI) available: Full experimental details and additional data for all the characterizations presented in the main text. Crystallographic data (including structure factors) for 1ΔΔ and 1ΛΛ have been deposited with the Cambridge Crystallographic Data Centre (CCDC 1839660-1839661, respectively). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc04917c

Autor: Euan K. Brechin, Stergios Piligkos, Peter W. Thulstrup, Rikke M. Gelardi, Andrei Rogalev, Wolfgang Wernsdorfer, Dmitri Mitcov, Marcel Ceccato, Anders Holmen Pedersen, Anders Reinholdt, Tue Hassenkam, Fabrice Wilhelm, Andreas Konstantatos, Morten Gotthold Vinum, Mikkel Sørensen

Publikováno v: Chemical Science
Mitcov, D, Pedersen, A H, Ceccato, M, Gelardi, R M, Hassenkam, T, Konstantatos, A, Reinholdt, A, Sorensen, M A, Thulstrup, P W, Vinum, M G, Wilhelm, F, Rogalev, A, Wernsdorfer, W, Brechin, E K & Piligkos, S 2019, ' Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet ', Chemical Science, vol. 10, no. 10, pp. 3065-3073 . https://doi.org/10.1039/C8SC04917C
Mitcov, D, Pedersen, A H, Ceccato, M, Gelardi, R M, Hassenkam, T, Konstantatos, A, Reinholdt, A, Sørensen, M A, Thulstrup, P W, Vinum, M G, Wilhelm, F, Rogalev, A, Wernsdorfer, W, Brechin, E K & Piligkos, S 2019, ' Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet ', Chemical Science, vol. 10, no. 10, pp. 3065-3073 . https://doi.org/10.1039/c8sc04917c
'Chemical Science ', vol: 10, pages: 3065-3073 (2019)

Simultaneous retention of SMM behaviour and of optical activity is demonstrated upon surface deposition for a chiral SMM.
The synthesis and characterization of a chiral, enneanuclear Mn(iii)-based, Single-Molecule Magnet, [Mn9O4(Me-sao)6(L)3(MeO

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2056a27c77dd2addc1f7ff68e75e0ff7
http://europepmc.org/articles/PMC6428142

[(VIVO)2M II5] (M = Ni, Co) Anderson wheels

Autor: Lucinda R. B. Wilson, Emily H. Payne, Gary S. Nichol, Arup Sarkar, Hector W. L. Fraser, Gopalan Rajaraman, Dmitri Mitcov, Stergios Piligkos, Euan K. Brechin

Publikováno v: Fraser, H W L, Payne, E H, Sarkar, A, Wilson, L R B, Mitcov, D, Nichol, G S, Rajaraman, G, Piligkos, S & Brechin, E K 2021, ' [(V IV O) 2 M II 5 ] (M = Ni, Co) Anderson wheels ', Dalton Transactions, vol. 50, no. 36, pp. 12495-12501 . https://doi.org/10.1039/D1DT01710A
Fraser, H W L, Payne, E H, Sarkar, A, Wilson, L R B, Mitcov, D, Nichol, G S, Rajaraman, G, Piligkos, S & Brechin, E K 2021, ' [(V IV O) 2 M II 5 ] (M = Ni, Co) Anderson wheels ', Dalton Transactions . https://doi.org/10.1039/D1DT01710A

Heterometallic Anderson wheels of formula [(VIVO)2MII5(hmp)10Cl2](ClO4)2·2MeOH (M = Ni, 1; Co, 2) have been synthesised from the solvothermal reaction of M(ClO4)2·6H2O and VCl3 with hmpH (2-(hydroxymethyl)pyridine). The metallic skeleton describes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ca945594ff4ad3ed207b11eeb520515c
https://curis.ku.dk/portal/da/publications/vivo2m-ii5-m--ni-co-anderson-wheels(b7a4cfc4-468c-40cc-8ed7-ed173e97acec).html