Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Dirk J. Beetstra"'
Autor:
Dirk J. Beetstra, Luigi Cavallo, Miasser Al-Ghamdi, Laura Falivene, F. A. Pasha, Sai V. C. Vummaleti
Publikováno v:
Organometallics. 36:1107-1112
Density functional theory calculations have been used to investigate competition between inner- and outer-sphere reaction pathways in the oxidative coupling of CO2 and ethylene for a set of 12 Ni–bisphosphine complexes, in order to build a QSAR app
Autor:
Daniel Tofan, Dirk J. Beetstra, Abdulaziz Al-Nezari, Christopher C. Cummins, Ioana Knopf, Khalid Al-Bahily
Publikováno v:
PMC
A family of cis-macrocyclic diphosphines was prepared in just three steps from white phosphorus and commercial materials using a modular synthetic approach. Alkylation of bicyclic diphosphane 3,4,8,9-tetramethyl-1,6-diphosphabicyclo(4.4.0)deca-3,8-di
Autor:
Dirk J. Beetstra, Laura Falivene, Sai V. C. Vummaleti, Jessica Scaranto, Albert Poater, Miasser Al-Ghamdi, Jason G. M. Morton, Luigi Cavallo
Publikováno v:
© Organometallics, 2015, vol. 34, núm. 23, p. 5549-5554
Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
instname
Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
instname
Density functional theory calculations have been used to investigate the reaction mechanism for the [Rh]-catalyzed intramolecular alkoxyacylation ([Rh] = [RhI(dppp)+] (dppp, 1,3-bis(diphenylphosphino)propane) and [Pd]/BPh3 dual catalytic system assis
Autor:
Abeer Abdulrahman Binobaid, Kingsley J. Cavell, Dirk J. Beetstra, Ian Andrew Fallis, Manuel Iglesias, Athanasia Dervisi
Publikováno v:
European Journal of Inorganic Chemistry. 2010:5426-5431
The performances of a number of RhI and IrI complexes of type [M(NHC)(COD)Cl] in the transfer hydrogenation of ketones were tested under a variety of reaction conditions, and with a variety of substrates, allowing comparison of Rh- and Ir-NHC complex
Autor:
Michael B. Hursthouse, Benson M. Kariuki, Dirk J. Beetstra, Ian Andrew Fallis, Athanasia Dervisi, Manuel Iglesias, Kingsley J. Cavell, William Clegg, Peter N. Horton, Simon J. Coles, Ross W. Harrington
Publikováno v:
European Journal of Inorganic Chemistry. 2010:1604-1607
An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels–Alder cycloadduct with CpH from which the RhI complexes may be prepared. Thus, structurally elaborate,
Autor:
Kingsley J. Cavell, Dirk J. Beetstra, Manuel Iglesias, Athanasia Dervisi, Ian Andrew Fallis, Benson M. Kariuki
Publikováno v:
European Journal of Inorganic Chemistry. 2009:1913-1919
The rhodium complexes [Rh(NHC)(COD)Cl] and cis-[Rh(NHC)(CO)2Cl] of seven-membered N-heterocyclic carbenes (NHC) bearing aromatic N-substituents (mesityl, xylyl and o-tolyl) were synthesised, and a comparison of their steric and electronic properties
Autor:
Gaifen Liu, Bart Hessen, Guohua Liu, Auke Meetsma, Xiaoquan Lu, Dirk J. Beetstra, Marcella Gagliardo
Publikováno v:
Organometallics, 27(10), 2316-2320. AMER CHEMICAL SOC INC
Reduction of the V(III) (beta-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [eta(5):eta(1-) C5H4(CH2)(2)NMe2]VCl2(PMe3) (1) with 1 equiv of Na/Hg yielded the V(II) dimer {[eta(5):eta(1)-C5H4(CH2)(2)NMe2]V(mu-Cl)}(2) (2). This compound reac
Autor:
Peter N. Horton, Athanasia Dervisi, Ian Andrew Fallis, Dirk J. Beetstra, Simon J. Coles, Andreas Stasch, Manuel Iglesias, Kingsley John Cavell, Michael B. Hursthouse
Publikováno v:
University of St Andrews CRIS
The synthesis of the novel seven-membered N-heterocyclic carbene (NHC) 1,3-dicyclohexyl-1,3-diazepan-2-ylidene (3) and its 5,6-dioxolane derivative 4 is reported and their coordination chemistry with Rh(I), Ir(I), and Pt(0) discussed. The M(cod)(3)Cl
Publikováno v:
Organometallics, 23(16), 3914-3920. AMER CHEMICAL SOC INC
The (N,N-dimethylaminoethyl)cyclopentadienyI vanadium(III) complex [eta(5),eta(1)-C5H4(CH2)(2)-NMe2]VCl2(PMe3) (1), in which the pendant amine is coordinated to the metal center, was prepared by the reaction Of VCl3(PMe3)(2) with Li[C5H4(CH2)(2)NMe2]
Publikováno v:
Organometallics. 19:4084-4089
The N-alkyl-2-(2,3,4,5-tetramethylcyclopentadienyl)ethylamines C5Me4H(CH2)2NHR (R = i-Pr, t-Bu) were obtained from the reaction of 2,3,4,5-tetramethylcyclopent-2-enone with deprotonated imines LiCH2CHNR followed by dehydration and reduction using LiA