Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Dimolybdenum tetraacetate"'
Autor:
Marcin Górecki, Jadwiga Frelek
Publikováno v:
Journal of Natural Products. 83:955-964
This critical appraisal is intended for users of the dimolybdenum method, well-established in electronic circular dichroism (ECD) to determine the absolute configuration of vic-diols and, in partic...
Publikováno v:
Phytochemistry. 189:112818
Eight undescribed humulane-type sesquiterpenoids (xanthspinol A-E, I, J and N), three undescribed germacrane-type sesquiterpenoids (xanthspinol F, G and O) and twelve known compounds were isolated from the fruits of Xanthium spinosum. The structures
Publikováno v:
Chemistry of Natural Compounds. 53:483-485
A new compound, notoginsenoside ST-7 (1), and one known compound notoginsenoside ST-1 (2), were isolated from notoginseng medicinal fungal substance. The structure of the new compound was elucidated by combined analysis of the 1D and 2D NMR data, the
Autor:
Chieh Hung Huang, Chih-Hua Chao, Ju-Chien Cheng, Shin-Hun Juang, Yu Ren Liao, Hsiu Hui Chan, De Yang Shen, Tian Shung Wu, Fu An Chen, Hung Cheng Shih, Hsin Yi Hung
Publikováno v:
RSC Advances. 5:41324-41331
The UV-guided isolation of polyacetylenes from the crude extract of Codonopsis pilosula has successfully led to the characterization of five new polyynes, pilosulynes A–E (1–5), and two new polyenes, pilosulynes F and G (6 and 7), as well as five
Autor:
RackSeon Seong, Jae-Kuk Yoo, Ui-Jung Youn, Ik-Soo Lee, Hyun-Ju Jung, KiHwan Bae, HongJin Kim, Byung Sun Min
Publikováno v:
Bulletin of the Korean Chemical Society. 29:1839-1842
Publikováno v:
The Journal of Organic Chemistry. 66:4819-4825
The method employing dimolybdenum tetraacetate for the assignment of the absolute configuration of optically active 1,2-diols is thoroughly revisited and applied to several compounds, some of which were synthesized by asymmetric cis-dihydroxylation.
Publikováno v:
Inorganica Chimica Acta. 304:305-308
The reaction between lithium bis(trimethylsilyl)benzamidinate and dimolybdenum tetraacetate yields a mixture of two stereoisomers: trans - ( 2a ) and cis -Mo 2 (O 2 CCH 3 ) 2 [PhC(NSi(CH 3 ) 3 ) 2 ] 2 ( 2b ). While the acetates coordinate to the Mo 2
Autor:
Wen-Jie Wang, Gui-Jie Zhang, Jing Qu, Hui Chen, Song Xu, Zhen-Feng Fang, Shuang-Gang Ma, Yang Liu, Shi-Shan Yu, Jian Bai
Publikováno v:
Planta medica. 79(2)
Four new abietane diterpenes ( 1 – 4 ) and two new cycloparvifloralone-type sesquiterpenoids ( 5 – 6 ) have been isolated from the twigs and leaves of Illicium majus , together with three known sesquiterpenoids and five known diterpenoids. Their
Publikováno v:
Journal of Asian natural products research. 13(10)
Two new furan derivatives named pollenfurans A (1) and B (2) were isolated from the ethyl acetate extract of bee-collected rape pollen. Their structures were elucidated by spectroscopic analysis. The absolute configurations of the 6,7-diol moiety in
Publikováno v:
Fresenius' Journal of Analytical Chemistry. 345:683-687
Bidentate complexes of dimolybdenum tetraacetate with 1,3-diaxial diols show Cotton effects around 490–540 nm (CD band I), 400–440 nm (II), 350–380 nm (III), 320 nm (IV) and 280 nm (V). The sign of the Cotton effect II can be predicted by a pro