Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Dimitris G. Vachliotis"'
Publikováno v:
Main Group Chemistry. 20:365-376
Sulfonates are well-known substances with a variety of applications, e.g. as surfactants. On the other hand, bis(sulfonates) bearing hydroxyl or keto group(s) in between the sulfonate groups can be used with or without further modification as startin
Publikováno v:
Main Group Chemistry. 18:365-381
Publikováno v:
Main Group Chemistry. 18:445-457
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 643:1075-1081
The compound Me2AsSI can exist in two different forms, either as dimethylarsinosulfenyl iodide [or (iodothio)dimethylarsane)], Me2As–S–I (A), or as dimethylthioarsinyl iodide (or dimethylarsinothioic iodide), Me2As(S)–I (B). To confirm that the
Publikováno v:
Main Group Chemistry. 16:125-139
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 641:1340-1346
Bunsen's cacodyl disulfide, Me2As(S)-S-AsMe2 (1), reacted with iodine giving the novel dimethylarsinosulfenyl iodide, Me2As-S-I (3) although theoretical calculations indicated that the AsV compound Me2As(S)-I (4) was more stable in the gas phase. The
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 641:710-714
The reactivity of Bunsen's cacodyl disulfide, Me2As(S)-S-AsMe2, towards nitrogen, phosphorus(III), oxygen and sulfur(II) nucleophiles was evaluated with the aim at identifying its electrophilic atom. The nitrogen nucleophiles either did not react or
Publikováno v:
Main Group Chemistry. 11:235-244
Publikováno v:
Main Group Chemistry. 11:267-273
Publikováno v:
Main Group Chemistry. 8:151-161
Molecular halides of group 13 in chloroform solutions interact but do not split Bunsen's cacodyl disulfide, Me2As(S)‒S‒AsMe2. With BF3 · Et2O cacodyl disulfide gives an equilibrated mixture of Me2As(S)‒S‒AsMe2 and Me2As‒SS‒AsMe2, whereas