Výsledky vyhledávání

Azido Derivatives of Low-Valent Group 14 Elements: Synthesis, Characterization, and Electronic Structure of [(n-Pr)2ATI]GeN3 and [(n-Pr)2ATI]SnN3 Featuring Heterobicyclic 10-π-Electron Ring Systems

Autor: Dias Hv, Dennis S. Marynick, Ashley E. Ayers

Publikováno v: Inorganic Chemistry. 39:4147-4151

Treatment of THF solutions of [(n-Pr)2ATI]MCl (where [(n-Pr)2ATI]- = N-(n-propyl)-2-(n-propylamino)troponiminate; M = Ge and Sn) with sodium azide affords the compounds [(n-Pr)2ATI]MN3 in excellent yield. X-ray analyses revealed that these Ge(II) and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6812de797bc04e5e35f4a529db02814b
https://doi.org/10.1021/ic000545u

Zobrazit plný text záznamu

Copper and Silver Complexes Containing Organic Azide Ligands: Syntheses, Structures, and Theoretical Investigation of [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) and [HB(3,5-(CF3)2Pz)3]AgN(1-Ad)NN (Where Pz = Pyrazolyl and 1-Ad = 1-Adamantyl)

Autor: S. A. Polach, Sor-Koon Goh, Dias Hv, Archibong Ef, Dennis S. Marynick

Publikováno v: Inorganic Chemistry. 39:3894-3901

Treatment of [HB(3,5-(CF3)2Pz)3]Na(THF) with CF3SO3Cu followed by 1-azidoadamantane affords [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) in 65% yield. The solid state structure shows that the copper atom is coordinated to the terminal nitrogen atom (NT) of the azi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::881a377a2a2c65464b8833a0c8c78edd
https://doi.org/10.1021/ic0004232

Zobrazit plný text záznamu

Adduct Formation or Metathesis Reactions of Silver Complexes Containing the Fluorinated Ligands [HB(3,5-(CF3)2Pz)3]- and [CF3SO3]-: Formation of Silver Adducts Containing Unsupported Silver−Germanium Bonds

Autor: Dias Hv, Ziyun Wang

Publikováno v: Inorganic Chemistry. 39:3890-3893

A mixture of [HB(3,5-(CF3)2Pz)3]Ag(eta 2-toluene) and [(Me)2ATI]GeCl in CH2Cl2, rather than undergoing metathesis, formed a 1:1 adduct [HB(3,5-(CF3)2Pz)3]Ag

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c42f0386048a09fe1bce9e7f25dd5cd4
https://doi.org/10.1021/ic000414t

Zobrazit plný text záznamu

Ethylene Oxide and Propylene Sulfide Complexes of Silver(I): Synthesis and Characterization of [HB(3,5-(CF3)2Pz)3]Ag(OC2H4) and [HB(3,5-(CF3)2Pz)3]Ag(SC3H6)

Autor: Dias Hv, Ziyun Wang

Publikováno v: Inorganic Chemistry. 39:3724-3727

The synthesis and solid-state structures of [HB(3,5-(CF3)2Pz)3]Ag(OC2H4) and [HB(3,5-(CF3)2Pz)3]Ag(SC3H6) are presented. The propylene sulfide ligand shows a relatively large tilt toward the [HB(3,5-(CF3)2Pz)3]Ag moiety compared to the ethylene oxide

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bdea5c8e72a72e132bc9259d62e005a0
https://doi.org/10.1021/ic991334w

Zobrazit plný text záznamu

Low-Valent Gallium, Indium, and Tin Compounds That Contain a Highly Fluorinated Tris(pyrazolyl)borate Ligand: Syntheses and Characterization of [HB(3,5-(CF3)2Pz)3]Ga, [HB(3,5-(CF3)2Pz)3]In, and [HB(3,5-(CF3)2Pz)3]Sn(CF3SO3)

Autor: Wiechang Jin, Dias Hv

Publikováno v: Inorganic Chemistry. 39:815-819

Syntheses and characterization of gallium(I), indium(I), and tin(II) complexes of the [HB(3,5-(CF3)2Pz)3]- ligand (where [HB(3,5-(CF3)2Pz)3]- = hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borate)) are reported. X-ray crystal structures of [HB(3,5-(CF

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fe1deabef9baf0c51e34faa7c1b033b7
https://doi.org/10.1021/ic9912171

Zobrazit plný text záznamu

Direct Synthesis of a Bis(pyrazolyl)boratocopper(I) Complex: Synthesis and Characterization of [H2B(3,5-(CF3)2Pz)2]Cu(PPh3)2 Displaying an Unusual Coordination Mode for a Poly(pyrazolyl)borate Ligand

Autor: Hui-Ling Lu, Dias Hv

Publikováno v: Inorganic Chemistry. 39:2246-2248

The synthesis of [H2B(3,5-(CF3)2Pz)2]Cu(PPh3)2 from (PPh3)2CuBH4 and 3,5-(CF3)2PzH and the solid state structure featuring an essentially monodentate coordination of a bis(pyrazolyl)borate ligand are described.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1860b74f96dc4d9df4bcb2e4d367f0e2
https://doi.org/10.1021/ic991385t

Zobrazit plný text záznamu

An isolable, oxygen-coordinated silver(I) complex of dimethyl diazomalonate: synthesis and characterization of [HB(3,5-(CF3)2Pz)3]Ag[OC(OCH3)]2CN2 (where Pz = pyrazolyl)

Autor: S. A. Polach, Dias Hv

Publikováno v: Inorganic chemistry. 39(21)

The use of a highly fluorinated tris(pyrazolyl)borate ligand to stabilize a silver(I) adduct containing dimethyl diazomalonate is described. [HB(3,5-(CF3)2Pz)3]Ag[OC(OCH3)]2CN2 is a thermally stabl...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::89e717f282bc01682d5f15ad409802bf
https://pubmed.ncbi.nlm.nih.gov/11196939

Zobrazit plný text záznamu

Synthesis and Structure of [TpBut2]In, a Highly Twisted [Tris(3,5-di-tert-butylpyrazolyl)hydroborato]indium(I) Complex: Comparison with the Re-Evaluated Ordered Structure of [TpBut]In

Autor: Simon G. Bott, M. C. Kuchta, Dias Hv, G. Parkin

Publikováno v: Inorganic Chemistry. 35:2708-2708

The indium(I) complex [Tp(Bu)()t()2]In ([Tp(Bu)()t()2] = tris(3,5-di-tert-butylpyrazolyl)hydroborato), synthesized by the reaction of [Tp(Bu)()t()2]Na with InCl, exhibits a structure in which the [Tp(Bu)()t()2] ligand adopts a highly twisted configur

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6bc5b3c7dcb83bd4c73ed6b3c18c3685
https://doi.org/10.1021/ic961981c

Zobrazit plný text záznamu

Akademický článek

Tento výsledek nelze pro nepřihlášené uživatele zobrazit.
K zobrazení výsledku je třeba se přihlásit.

Akademický článek

Tento výsledek nelze pro nepřihlášené uživatele zobrazit.
K zobrazení výsledku je třeba se přihlásit.

Vyhledávací nástroje:

Upřesnit hledání