Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]

Autor: Andrei-Cristian Gheorghe, Yurii S. Bibik, Olesia I. Kucheriv, Diana D. Barakhtii, Marin-Vlad Boicu, Ionela Rusu, Andrei Diaconu, Il’ya A. Gural’skiy, Gábor Molnár, Aurelian Rotaru

Publikováno v: Magnetochemistry, Vol 6, Iss 3, p 31 (2020)

We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)2}2]. By applying an external pressure (up to 3 kbar), we were able to tune the charge transpo

Externí odkaz: https://doaj.org/article/26f1954330c147669d5e8bd3de6011c6

Crystal structure of catena -poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

Autor: Diana D. Barakhtii, Olesia I. Kucheriv, Sergey O. Malinkin, Sergiu Shova, Il'ya A. Gural'skiy

Publikováno v: Acta Crystallographica Section E Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 8, Pp 1149-1152 (2019)
Acta Crystallographica Section E: Crystallographic Communications

Cyanide anions bridge FeII and AuI cations to form a one-dimensional polymeric compound with free di­cyano­aurate anions.
In the title polymeric complex, {[Fe(CN)2(C10H8N2)2(H2O)2][Au(CN)2]}n, the FeII ion, which is located on a twofold rotati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::feba04b7979be248e6f1af8b47f0bc8a