Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Dhanarajan Arunprasath"'
Publikováno v:
Org Chem Front
A metal-free aromative cascade has been developed for the synthesis of diverse heterocycles from readily accessible hydroxy/aminochalcones and acid/alkyl halides. The cascade being by a base-mediated intramolecular aldol cyclization/dehydration seque
Publikováno v:
Journal of Catalysis. 377:673-683
Transition-metal nanoparticles (NPs) gained interest as a catalyst due to their high reactivity and recyclability. Monometallic NPs are less catalytic active compared to homogeneous counterparts as less number of catalytic active metal atoms are pres
Publikováno v:
Advanced Synthesis & Catalysis. 361:1172-1207
Publikováno v:
The Journal of Organic Chemistry. 83:11298-11308
A facile synthesis of indanone-fused spirooxindoles is disclosed by directing the reactivity of η3-oxoallyl Pd-intermediate toward 5-exo-trig mode of cyclization. The Pd-catalyzed reaction of the rationally designed starting material 3-arylidene oxi
Publikováno v:
The Journal of Organic Chemistry. 83:4692-4702
The carbene migratory insertion involving a domino reaction by highly stable, reusable, and binaphthyl-stabilized Pd-nanoparticles (Pd-BNP) is disclosed. The reaction was catalyzed by 2 mol % of a heterogeneous Pd-BNP catalyst under external ligand-f
Publikováno v:
Advanced Synthesis & Catalysis. 359:698-708
A transition-metal-free and base-mediated carbene insertion across sulfur-sulfur and selenium-selenium bonds has been developed by employing N-tosylhydrazone as a stable and safe carbene precursor. The ylide formation from carbene followed by Stevens
Publikováno v:
Organic Letters. 17:5448-5451
A domino process that converges the migratory insertion of carbene with a Heck reaction has been established as a versatile tool for the synthesis of 2-arylidene-3-aryl-1-indanones from very stable and easily accessible N-tosylhydrazones and 2'-iodoc
Publikováno v:
Organic letters. 19(19)
An efficient diastereoselective synthesis of α-tetralone-fused spirooxindoles is reported. The Pd-catalyzed domino reaction proceeds through a carbene migratory insertion followed by a 6-endo-trig mode of conjugate addition sequence from easily acce
Publikováno v:
ChemInform. 47
Tosylhydrazones from arylaldehydes and 2-iodochalcones react under Pd catalysis to give the title compounds in high yields.
Publikováno v:
ChemInform. 46
Transition metal free Bronsted acid mediated synthesis of biologically important pyrido[1,2-a]indole scaffolds through aza-Nazarov type cyclization of readily available diaryl(2-pyridyl)methanol using formic acid has been developed. This methodology