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Autor:
Yisong Guo, Jhih-Liang Huang, Xinyu Liu, Yijie Tang, Xinglin Jia, Dev Sanyal, Wei-Chen Chang, Cheng-Ping Yu
Publikováno v:
Biochemistry. 57(12)
Two non-heme iron enzymes, IsnB and AmbI3, catalyze a novel decarboxylation-assisted olefination to produce indole vinyl isonitrile, an important building block for many natural products. Compared to other reactions catalyzed by this enzyme family, d