Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Desmond G. Hellier"'
Autor:
David C. Ayres, Desmond G. Hellier
A quick reference for information on chemicals of environmental importance, this dictionary has been carefully compiled and designed to make it useful for students. About 600 substances are covered in alphabetically arranged entries: these include so
Publikováno v:
Israel Journal of Chemistry. 20:133-136
Reaction of 1,1-diphenyl-propane-1,3-diol with thionyl-chloride gave a product, which was identified by X-ray analysis as 3,3-diphenyl-1,2-oxathiolane-2,2-dioxide. The compound crystallizes at room temperature in the monoclinic space group Pt/n with
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :190-193
The conformational analysis of ethylene sulphites is discussed and for two sulphites an attempt is made to calculate the twist-envelope proportions.
Autor:
Desmond G. Hellier, Gerald W. Buchanan
Publikováno v:
Canadian Journal of Chemistry. 54:1428-1432
13C nmr chemical shifts for ethylene sulfite and 17 derivatives are presented. From the magnitudes of the γ shifts and the tenets of conformational analysis, support is gained for the existence of twist-envelope conformations in solution. Pseudorota
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :919-923
Reduction by LiAlH4 of 2,2,4,6,6-pentamethylheptane-3,5-dione gives a mixture of diastereoisomeric diols, which upon cyclisation with thionyl chloride yields a mixture of isomeric 4,6-di-t-butyl-5-methyl-1,3,2-dioxathiane 2-oxide. From the distributi
Autor:
Desmond G. Hellier, H. G. Liddy
Publikováno v:
Magnetic Resonance in Chemistry. 26:671-674
Les sulfates cycliques a 6 chainons different des sulfites cycliques par le fait qu'ils n'existent pas sous la forme chaise rigide en solution a temperature ordinaire. L'effet anomere stabilise le cycle sulfite mais pour les sulfates trimethylenes, l
Autor:
Frederick J. Webb, Desmond G. Hellier
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :612-616
The i.r. and Raman spectra of twenty-five methyl-substituted trimethylene sulphites (1,3,2-dioxathian 2-oxides) have been examined in the 1 400–250 cm–1 region. A number of bands have been assigned and appear to be characteristic of alkyl 1,3,2-d
Autor:
Desmond G. Hellier, H. Glendon Liddy
Publikováno v:
Magnetic Resonance in Chemistry. 27:431-436
The stereoisomerism of some methyl-substituted 1,3,2-dioxathiepanes has been investigated by 13C and 17O NMR spectroscopy. The effects of substituents on the conformational equilibria of the seven-membered rings are discussed and compared with those
Autor:
Desmond G. Hellier, Frederick J. Webb
Publikováno v:
Organic Magnetic Resonance. 9:347-350
The high resolution proton magnetic resonance spectra of a series of cyclic inorganic esters and analogous 1,3-dioxans have been analysed. The coupling constants and chemical shifts involved indicate that most of the compounds exist preferentially in
Autor:
Desmond G. Hellier, Andrew M. Phillips
Publikováno v:
Organic Magnetic Resonance. 18:178-183
13C NMR chemical shifts for trimethylene sulphite and 35 derivatives are presented. From the magnitudes of the β shifts it has been possible to establish chemical shift additivity relationships for a series of compounds. The results are discussed in