Couple-close construction of non-classical boron cluster-phosphonium conjugates

Autor: Zhaofeng Sun, Jibo Zong, Hongyuan Ren, Changsheng Lu, Deshuang Tu, Jordi Poater, Miquel Solà, Zhuangzhi Shi, Hong Yan

Publikováno v: Nature Communications, Vol 15, Iss 1, Pp 1-11 (2024)

Abstract Heteropolycyclic molecular systems, which are essential components in the fields of materials and pharmacology, frequently consist of 2D extended organic aromatic rings. Here, we introduce a type of inorganic-organic hybrid 3D conjugates by

Externí odkaz: https://doaj.org/article/29150e35013e40618984f58831837fb2

Molecular engineering of AIE-active boron clustoluminogens for enhanced boron neutron capture therapy.

Autor: Wenli Ma, Yanyang Wang, Yilin Xue, Mengmeng Wang, Changsheng Lu, Wanhua Guo, Yuan-Hao Liu, Diyun Shu, Guoqiang Shao, Qinfeng Xu, Deshuang Tu, Hong Yan

Publikováno v: Chemical Science; 3/21/2024, Vol. 15 Issue 11, p4019-4030, 12p

Cage–···Cage– Interaction: Boron Cluster-Based Noncovalent Bond and Its Applications in Solid-State Materials

Autor: Fangxiang Sun, Hong Yan, Jiaxin Li, Miquel Solà, Jordi Poater, Deshuang Tu

Publikováno v: JACS Au, Vol 1, Iss 11, Pp 2047-2057 (2021)
JACS Au, 2021, vol. 1, núm. 11, p. 2047-2057
Articles publicats (D-Q)
Tu, Deshuang Li, Jiaxin Sun, Fangxiang Yan, Hong Poater i Teixidor, Jordi Solà i Puig, Miquel 2021 Cage-···Cage-Interaction: A Boron Cluster-Based Noncovalent Bond and Its Applications in Solid-State Materials JACS Au 1 11 2047 2057
DUGiDocs – Universitat de Girona
instname
JACS Au

Carboranes are boron-carbon clusters with important applications in fields of materials, catalysis, pharmaceuticals, etc. However, the non-covalent interactions that could determine the solid-state structures and properties of such boron clusters hav

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cf7aff7145ac02a07109e0ca0fded336
https://doaj.org/article/8797f747e798430eb23cba1a0288398f

Palladium-Catalyzed Hydroboration of Alkynes with Carboranes: Facile Construction of a Library of Boron Cluster-Based AIE-Active Luminogens

Autor: Fangxiang Sun, Shuaimin Tan, Hou‐Ji Cao, Jingkai Xu, Vladimir I. Bregadze, Deshuang Tu, Changsheng Lu, Hong Yan

Publikováno v: Angewandte Chemie (International ed. in English). 61(33)

The classical aggregation-induced emission (AIE)-active luminogens (AIEgens) usually include two-dimensional aromatic systems such as tetraphenylethenes, which are synthesized in several steps by using toxic additives. Here, we proposed a new molecul

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3474d2a58fc7aea11eddb59d4ee27086
https://pubmed.ncbi.nlm.nih.gov/35665583

The nido ‐Cage⋅⋅⋅π Bond: A Non‐covalent Interaction between Boron Clusters and Aromatic Rings and Its Applications

Autor: Jordi Poater i Teixidor, Hong Yan, Miquel Solà i Puig, Deshuang Tu

Publikováno v: Angewandte Chemie International Edition. 59:9018-9025

Non-covalent interactions involving multicenter multielectron skeletons such as boron clusters are rare. Now, a non-covalent interaction, the nido-cage⋅⋅⋅π bond, is discovered based on the boron cluster C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c30df623a8d778c099d6a50d1960de0d
https://doi.org/10.1002/anie.201915290