Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Derrik S. Helfer"'
Publikováno v:
Organometallics. 25:410-415
Reactions of alkenols with cis-Pt(Cl)2(TPPTS)2 (TPPTS = P(m-C6H4SO3Na)3) in water result in [Pt(η3-allyl)(TPPTS)2]+ as the exclusive platinum product with 1 equiv of oxidized alkenol. The η3-allyl is not fluxional in water, and the syn and anti iso
Autor:
Jim D. Atwood, Derrik S. Helfer
Publikováno v:
Organometallics. 23:2412-2420
Reactions of alkenes (ethylene, propene, and 1-hexene) with water in the presence of cis-Pt(Cl)2(TPPTS)2 (TPPTS = P(m-C6H4SO3Na)3) produces stoichiometrically the Wacker oxidation product (acetalde...
Publikováno v:
Organometallics. 22:826-833
Several water-soluble platinum(II) complexes containing methyl ligands have been prepared, PtMe2L2 and Pt(Cl)(Me)L2 (L2 = two P(m-C6H4SO3Na)3, TPPTS; (m-C6H4SO3Na)2PCH2CH2P(m-C6H4SO3Na2), DPPETS; (m-C6H4SO3Na)2PCH2CH2CH2P(m-C6H4SO3Na)2, DPPPTS; or (m
Autor:
Jim D. Atwood, Derrik S. Helfer and
Publikováno v:
Organometallics. 21:250-252
The oxidation state for platinum complexes of TPPTS can be controlled through variation of the pH of an aqueous solution. Thus Pt(H)(TPPTS)3+ dissolved in H2O gives a well-characterized Pt(II)−H complex at neutral or acidic pH but exists as Pt(TPPT